catena-Poly[[[aqua­(glycine-κO)lithium]-μ-glycine-κ(2) O:O′] bromide]

In the title coordination polymer, {[Li(C(2)H(5)NO(2))(2)(H(2)O)]Br}(n), the Li(+) cation is coordinated by three carboxyl­ate O atoms of zwitterionic glycine mol­ecules and by a water mol­ecule, forming a distorted tetra­hedral geometry. One of the two glycine mol­ecules bridges neighbouring comple...

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Detalles Bibliográficos
Autores principales: Balakrishnan, T., Ramamurthi, K., Jeyakanthan, J., Thamotharan, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588392/
https://www.ncbi.nlm.nih.gov/pubmed/23476353
http://dx.doi.org/10.1107/S1600536812050660
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author Balakrishnan, T.
Ramamurthi, K.
Jeyakanthan, J.
Thamotharan, S.
author_facet Balakrishnan, T.
Ramamurthi, K.
Jeyakanthan, J.
Thamotharan, S.
author_sort Balakrishnan, T.
collection PubMed
description In the title coordination polymer, {[Li(C(2)H(5)NO(2))(2)(H(2)O)]Br}(n), the Li(+) cation is coordinated by three carboxyl­ate O atoms of zwitterionic glycine mol­ecules and by a water mol­ecule, forming a distorted tetra­hedral geometry. One of the two glycine mol­ecules bridges neighbouring complexes, forming an infinite chain parallel to the c axis. Polymeric chains are further linked by extensive hydrogen bonds involving the Br(−) anions and glycine and water mol­ecules, producing a three-dimensional network.
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spelling pubmed-35883922013-03-08 catena-Poly[[[aqua­(glycine-κO)lithium]-μ-glycine-κ(2) O:O′] bromide] Balakrishnan, T. Ramamurthi, K. Jeyakanthan, J. Thamotharan, S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Li(C(2)H(5)NO(2))(2)(H(2)O)]Br}(n), the Li(+) cation is coordinated by three carboxyl­ate O atoms of zwitterionic glycine mol­ecules and by a water mol­ecule, forming a distorted tetra­hedral geometry. One of the two glycine mol­ecules bridges neighbouring complexes, forming an infinite chain parallel to the c axis. Polymeric chains are further linked by extensive hydrogen bonds involving the Br(−) anions and glycine and water mol­ecules, producing a three-dimensional network. International Union of Crystallography 2012-12-19 /pmc/articles/PMC3588392/ /pubmed/23476353 http://dx.doi.org/10.1107/S1600536812050660 Text en © Balakrishnan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Balakrishnan, T.
Ramamurthi, K.
Jeyakanthan, J.
Thamotharan, S.
catena-Poly[[[aqua­(glycine-κO)lithium]-μ-glycine-κ(2) O:O′] bromide]
title catena-Poly[[[aqua­(glycine-κO)lithium]-μ-glycine-κ(2) O:O′] bromide]
title_full catena-Poly[[[aqua­(glycine-κO)lithium]-μ-glycine-κ(2) O:O′] bromide]
title_fullStr catena-Poly[[[aqua­(glycine-κO)lithium]-μ-glycine-κ(2) O:O′] bromide]
title_full_unstemmed catena-Poly[[[aqua­(glycine-κO)lithium]-μ-glycine-κ(2) O:O′] bromide]
title_short catena-Poly[[[aqua­(glycine-κO)lithium]-μ-glycine-κ(2) O:O′] bromide]
title_sort catena-poly[[[aqua­(glycine-κo)lithium]-μ-glycine-κ(2) o:o′] bromide]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588392/
https://www.ncbi.nlm.nih.gov/pubmed/23476353
http://dx.doi.org/10.1107/S1600536812050660
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