Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ido-κN (1)}cobalt(II)

In the centrosymmetic title complex, [Co(C(18)H(12)N(5))(2)(H(2)O)(2)], the Co(II) ion is coordinated by two N,N′-bidentate 5-(pyridin-2-yl)-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ide ligands and two water mol­ecules in a trans-CoO(2)N(4) coordination geometry. In the ligand, the dihedral an...

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Detalles Bibliográficos
Autor principal: Li, Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588412/
https://www.ncbi.nlm.nih.gov/pubmed/23476489
http://dx.doi.org/10.1107/S1600536813003243
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author Li, Bin
author_facet Li, Bin
author_sort Li, Bin
collection PubMed
description In the centrosymmetic title complex, [Co(C(18)H(12)N(5))(2)(H(2)O)(2)], the Co(II) ion is coordinated by two N,N′-bidentate 5-(pyridin-2-yl)-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ide ligands and two water mol­ecules in a trans-CoO(2)N(4) coordination geometry. In the ligand, the dihedral angles between the triazole ring and its adjacent pyridine and benzene rings are 5.57 (14) and 6.89 (16)°, respectively. In the crystal, mol­ecules are linked by O—H⋯N hydrogen bonds, generating a three-dimensional network.
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spelling pubmed-35884122013-03-08 Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ido-κN (1)}cobalt(II) Li, Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetic title complex, [Co(C(18)H(12)N(5))(2)(H(2)O)(2)], the Co(II) ion is coordinated by two N,N′-bidentate 5-(pyridin-2-yl)-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ide ligands and two water mol­ecules in a trans-CoO(2)N(4) coordination geometry. In the ligand, the dihedral angles between the triazole ring and its adjacent pyridine and benzene rings are 5.57 (14) and 6.89 (16)°, respectively. In the crystal, mol­ecules are linked by O—H⋯N hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2013-02-06 /pmc/articles/PMC3588412/ /pubmed/23476489 http://dx.doi.org/10.1107/S1600536813003243 Text en © Bin Li 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Bin
Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ido-κN (1)}cobalt(II)
title Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ido-κN (1)}cobalt(II)
title_full Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ido-κN (1)}cobalt(II)
title_fullStr Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ido-κN (1)}cobalt(II)
title_full_unstemmed Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ido-κN (1)}cobalt(II)
title_short Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ido-κN (1)}cobalt(II)
title_sort diaqua­bis­{5-(pyridin-2-yl-κn)-3-[4-(pyridin-4-yl)phen­yl]-1h-1,2,4-triazol-1-ido-κn (1)}cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588412/
https://www.ncbi.nlm.nih.gov/pubmed/23476489
http://dx.doi.org/10.1107/S1600536813003243
work_keys_str_mv AT libin diaquabis5pyridin2ylkn34pyridin4ylphenyl1h124triazol1idokn1cobaltii

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