(±)-(4aR,5R,8S,8aR)-8-(tert-Butyl­dimethyl­sil­yloxy)-2,5,8a-trimethyl-4a,5,8,8a-tetra­hydro­naphthalene-1,4-dione

In the title compound, C(19)H(30)O(3)Si, both rings adopt a half-boat conformation. Overall, the mol­ecule approximates a U-shape as the cyclo-2-ene-1,4-dione and butyl­dimethyl­sil­yloxy substituents lie to the same side of the central cyclo­hexene ring; the methyl substituent lies to the other sid...

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Detalles Bibliográficos
Autores principales: Delling, Felix N., Zukerman-Schpector, Julio, Brocksom, Timothy J., Brocksom, Ursula, Finelli, Fernanda G., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588414/
https://www.ncbi.nlm.nih.gov/pubmed/23476523
http://dx.doi.org/10.1107/S1600536813002973
Descripción
Sumario:In the title compound, C(19)H(30)O(3)Si, both rings adopt a half-boat conformation. Overall, the mol­ecule approximates a U-shape as the cyclo-2-ene-1,4-dione and butyl­dimethyl­sil­yloxy substituents lie to the same side of the central cyclo­hexene ring; the methyl substituent lies to the other side of the mol­ecule. In the crystal, linear supra­molecular chains along the b axis are sustained by C—H⋯O inter­actions.

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