Bis[2-(thio­phen-2-yl)quinoxaline-κN (4)]silver(I) tetra­fluoridoborate

In the title compound, [Ag(C(12)H(8)N(2)S)(2)]BF(4), the two-coordinate Ag(I) ion lies on a crystallographic inversion center and is linearly bonded to the N-donor atoms of two separate quinoxaline ligands. The thio­phenyl ring of the ligand is nearly coplanar with the quinoxaline ring system [dihed...

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Detalles Bibliográficos
Autor principal: Crundwell, Guy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588418/
https://www.ncbi.nlm.nih.gov/pubmed/23476506
http://dx.doi.org/10.1107/S1600536813004510
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author Crundwell, Guy
author_facet Crundwell, Guy
author_sort Crundwell, Guy
collection PubMed
description In the title compound, [Ag(C(12)H(8)N(2)S)(2)]BF(4), the two-coordinate Ag(I) ion lies on a crystallographic inversion center and is linearly bonded to the N-donor atoms of two separate quinoxaline ligands. The thio­phenyl ring of the ligand is nearly coplanar with the quinoxaline ring system [dihedral angle = 9.15 (13)°]. In the crystal, the complex mol­ecules pack in layers parallel to (-102) and form weak π–π ring stacking inter­actions [minimum ring centroid separation = 3.7054 (17) Å]. The tetra­fluoridoroborate anion is equally disordered about an inversion center.
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spelling pubmed-35884182013-03-08 Bis[2-(thio­phen-2-yl)quinoxaline-κN (4)]silver(I) tetra­fluoridoborate Crundwell, Guy Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(C(12)H(8)N(2)S)(2)]BF(4), the two-coordinate Ag(I) ion lies on a crystallographic inversion center and is linearly bonded to the N-donor atoms of two separate quinoxaline ligands. The thio­phenyl ring of the ligand is nearly coplanar with the quinoxaline ring system [dihedral angle = 9.15 (13)°]. In the crystal, the complex mol­ecules pack in layers parallel to (-102) and form weak π–π ring stacking inter­actions [minimum ring centroid separation = 3.7054 (17) Å]. The tetra­fluoridoroborate anion is equally disordered about an inversion center. International Union of Crystallography 2013-02-23 /pmc/articles/PMC3588418/ /pubmed/23476506 http://dx.doi.org/10.1107/S1600536813004510 Text en © Guy Crundwell 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Crundwell, Guy
Bis[2-(thio­phen-2-yl)quinoxaline-κN (4)]silver(I) tetra­fluoridoborate
title Bis[2-(thio­phen-2-yl)quinoxaline-κN (4)]silver(I) tetra­fluoridoborate
title_full Bis[2-(thio­phen-2-yl)quinoxaline-κN (4)]silver(I) tetra­fluoridoborate
title_fullStr Bis[2-(thio­phen-2-yl)quinoxaline-κN (4)]silver(I) tetra­fluoridoborate
title_full_unstemmed Bis[2-(thio­phen-2-yl)quinoxaline-κN (4)]silver(I) tetra­fluoridoborate
title_short Bis[2-(thio­phen-2-yl)quinoxaline-κN (4)]silver(I) tetra­fluoridoborate
title_sort bis[2-(thio­phen-2-yl)quinoxaline-κn (4)]silver(i) tetra­fluoridoborate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588418/
https://www.ncbi.nlm.nih.gov/pubmed/23476506
http://dx.doi.org/10.1107/S1600536813004510
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