The halogen-bonded adduct 1,4-bis(pyri­din-4-yl)buta-1,3-diyne–1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexa­deca­fluoro-1,8-diiodo­octane (1/1)

In the crystal structure of the title compound, C(8)F(16)I(2)·C(14)H(8)N(2), the mol­ecules form infinite chains parallel to [2-11] through two symmetry-independent C—I⋯N halogen bonds (XBs). As commonly found, the perfluoro­alkyl mol­ecules segregate from the hydro­carbon ones, forming a layered structure. Apart from the XBs, the only contact below the sum of van der Waals radii is a weak H⋯F contact. The topology of the network is a nice example of the paradigm of the expansion of ditopic starting modules; the XB leads to the construction of infinite supramolecular chains along [2-11] formed by alternating XB donors and acceptors.