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(Pyridine-2-aldoximato-κ(2) N,N′)bis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
In the title complex, [Ir(C(11)H(8)N)(2)(C(6)H(5)N(2)O)], the octahedrally coordinated Ir(III) atom is bonded to two 2-(pyridin-2-yl)phenyl ligands, through two phenyl C and two pydidine N atoms, and to one pyridine-2-aldoxime ligand through a pyridine N and an oxime N atom. The oxime O atom of the...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588427/ https://www.ncbi.nlm.nih.gov/pubmed/23476503 http://dx.doi.org/10.1107/S1600536813004297 |
| _version_ | 1782261563277705216 |
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| author | Pal, Satyanarayan Singh, Bimal Chandra |
| author_facet | Pal, Satyanarayan Singh, Bimal Chandra |
| author_sort | Pal, Satyanarayan |
| collection | PubMed |
| description | In the title complex, [Ir(C(11)H(8)N)(2)(C(6)H(5)N(2)O)], the octahedrally coordinated Ir(III) atom is bonded to two 2-(pyridin-2-yl)phenyl ligands, through two phenyl C and two pydidine N atoms, and to one pyridine-2-aldoxime ligand through a pyridine N and an oxime N atom. The oxime O atom of the aldoxime unit forms intermolecular C—H⋯O hydrogen bonds, which result in a two-dimensional hydrogen-bonded polymeric network parallel to (100). C—H⋯π interactions are also observed. |
| format | Online Article Text |
| id | pubmed-3588427 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35884272013-03-08 (Pyridine-2-aldoximato-κ(2) N,N′)bis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) Pal, Satyanarayan Singh, Bimal Chandra Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ir(C(11)H(8)N)(2)(C(6)H(5)N(2)O)], the octahedrally coordinated Ir(III) atom is bonded to two 2-(pyridin-2-yl)phenyl ligands, through two phenyl C and two pydidine N atoms, and to one pyridine-2-aldoxime ligand through a pyridine N and an oxime N atom. The oxime O atom of the aldoxime unit forms intermolecular C—H⋯O hydrogen bonds, which result in a two-dimensional hydrogen-bonded polymeric network parallel to (100). C—H⋯π interactions are also observed. International Union of Crystallography 2013-02-20 /pmc/articles/PMC3588427/ /pubmed/23476503 http://dx.doi.org/10.1107/S1600536813004297 Text en © Pal and Singh 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Pal, Satyanarayan Singh, Bimal Chandra (Pyridine-2-aldoximato-κ(2) N,N′)bis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) |
| title | (Pyridine-2-aldoximato-κ(2)
N,N′)bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
| title_full | (Pyridine-2-aldoximato-κ(2)
N,N′)bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
| title_fullStr | (Pyridine-2-aldoximato-κ(2)
N,N′)bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
| title_full_unstemmed | (Pyridine-2-aldoximato-κ(2)
N,N′)bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
| title_short | (Pyridine-2-aldoximato-κ(2)
N,N′)bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
| title_sort | (pyridine-2-aldoximato-κ(2)
n,n′)bis[2-(pyridin-2-yl)phenyl-κ(2)
c
(1),n]iridium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588427/ https://www.ncbi.nlm.nih.gov/pubmed/23476503 http://dx.doi.org/10.1107/S1600536813004297 |
| work_keys_str_mv | AT palsatyanarayan pyridine2aldoximatok2nnbis2pyridin2ylphenylk2c1niridiumiii AT singhbimalchandra pyridine2aldoximatok2nnbis2pyridin2ylphenylk2c1niridiumiii |