3,3′-(1-Oxopropane-1,3-di­yl)bis­(1,3-thia­zolidine-2-thione) chloro­benzene hemisolvate

The title compound, C(9)H(12)N(2)OS(4)·0.5C(6)H(5)Cl, which contains two 1,3-thia­zolidine-2-thione rings, is a by-product of the synthesis of 3-acryloyl-1,3-thia­zolidine-2-thione. The dihedral angle between these rings is 79.95 (9)°, with both rings displaying a twisted conformation. The twist ang...

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Detalles Bibliográficos
Autores principales: Franzel, Christine, Purdy, Andrew, Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588431/
https://www.ncbi.nlm.nih.gov/pubmed/23476562
http://dx.doi.org/10.1107/S1600536813003292
Descripción
Sumario:The title compound, C(9)H(12)N(2)OS(4)·0.5C(6)H(5)Cl, which contains two 1,3-thia­zolidine-2-thione rings, is a by-product of the synthesis of 3-acryloyl-1,3-thia­zolidine-2-thione. The dihedral angle between these rings is 79.95 (9)°, with both rings displaying a twisted conformation. The twist angle of the amide group is 5.6 (1)°. In the crystal, the molecules are linked into [001] chains by C—H⋯O interactions. The chloro­benzene solvent mol­ecule was found to show unresolvable disorder about a centre of inversion and its contribution to the scattering was removed with the SQUEEZE option in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155].

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