2-(4-Fluoro­phen­yl)-1-(4-meth­oxy­phen­yl)-1H-phenanthro[9,10-d]imidazole

In the title compound, C(28)H(19)FN(2)O, the phenanthrene fused with an imidazole ring, constituting an essentially planar tetra­cyclic system [maximum deviation = 0.032 (2) Å], makes dihedral angles of 60.83 (4) and 80.55 (4)° with the fluoro­benzene and meth­oxy­benzene rings, respectively. The di...

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Autores principales: Mohandas, T., Sathishkumar, R., Sakthivel, P., Jayabharathi, J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588432/
https://www.ncbi.nlm.nih.gov/pubmed/23476557
http://dx.doi.org/10.1107/S1600536813003504
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author Mohandas, T.
Sathishkumar, R.
Sakthivel, P.
Jayabharathi, J.
author_facet Mohandas, T.
Sathishkumar, R.
Sakthivel, P.
Jayabharathi, J.
author_sort Mohandas, T.
collection PubMed
description In the title compound, C(28)H(19)FN(2)O, the phenanthrene fused with an imidazole ring, constituting an essentially planar tetra­cyclic system [maximum deviation = 0.032 (2) Å], makes dihedral angles of 60.83 (4) and 80.55 (4)° with the fluoro­benzene and meth­oxy­benzene rings, respectively. The dihedral angle between the the meth­oxy­benzene and fluoro­benzene rings is 69.45 (6)°. In the crystal, C—H⋯O hydrogen bonds connect the mol­ecules into infinite strands along the b axis. The crystal structure is further consolidated by C—H⋯π inter­actions.
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spelling pubmed-35884322013-03-08 2-(4-Fluoro­phen­yl)-1-(4-meth­oxy­phen­yl)-1H-phenanthro[9,10-d]imidazole Mohandas, T. Sathishkumar, R. Sakthivel, P. Jayabharathi, J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(19)FN(2)O, the phenanthrene fused with an imidazole ring, constituting an essentially planar tetra­cyclic system [maximum deviation = 0.032 (2) Å], makes dihedral angles of 60.83 (4) and 80.55 (4)° with the fluoro­benzene and meth­oxy­benzene rings, respectively. The dihedral angle between the the meth­oxy­benzene and fluoro­benzene rings is 69.45 (6)°. In the crystal, C—H⋯O hydrogen bonds connect the mol­ecules into infinite strands along the b axis. The crystal structure is further consolidated by C—H⋯π inter­actions. International Union of Crystallography 2013-02-09 /pmc/articles/PMC3588432/ /pubmed/23476557 http://dx.doi.org/10.1107/S1600536813003504 Text en © Mohandas et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mohandas, T.
Sathishkumar, R.
Sakthivel, P.
Jayabharathi, J.
2-(4-Fluoro­phen­yl)-1-(4-meth­oxy­phen­yl)-1H-phenanthro[9,10-d]imidazole
title 2-(4-Fluoro­phen­yl)-1-(4-meth­oxy­phen­yl)-1H-phenanthro[9,10-d]imidazole
title_full 2-(4-Fluoro­phen­yl)-1-(4-meth­oxy­phen­yl)-1H-phenanthro[9,10-d]imidazole
title_fullStr 2-(4-Fluoro­phen­yl)-1-(4-meth­oxy­phen­yl)-1H-phenanthro[9,10-d]imidazole
title_full_unstemmed 2-(4-Fluoro­phen­yl)-1-(4-meth­oxy­phen­yl)-1H-phenanthro[9,10-d]imidazole
title_short 2-(4-Fluoro­phen­yl)-1-(4-meth­oxy­phen­yl)-1H-phenanthro[9,10-d]imidazole
title_sort 2-(4-fluoro­phen­yl)-1-(4-meth­oxy­phen­yl)-1h-phenanthro[9,10-d]imidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588432/
https://www.ncbi.nlm.nih.gov/pubmed/23476557
http://dx.doi.org/10.1107/S1600536813003504
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