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Tris[dimethyl (benzoyl­amido)­phosphato-κ(2) O,O′](1,10-phenanthroline-κ(2) N,N′)neodymium(III)

In both independent mol­ecules of the title compound, [Nd(C(9)H(11)NO(4)P)(3)(C(12)H(8)N(2))], the Nd(III) atom is coordinated by six O atoms belonging to three phosphoryl ligands and two N atoms of 1,10-phenanthroline in a dodeca­hedral geometry. In the phosphoryl ligands, the benzene rings are twi...

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Autores principales: Kariaka, Nataliia S., Trush, Victor A., Medviediev, Volodymyr V., Sliva, Tetyana Yu., Amirkhanov, Vladimir M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588435/
https://www.ncbi.nlm.nih.gov/pubmed/23476491
http://dx.doi.org/10.1107/S1600536813003462
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author Kariaka, Nataliia S.
Trush, Victor A.
Medviediev, Volodymyr V.
Sliva, Tetyana Yu.
Amirkhanov, Vladimir M.
author_facet Kariaka, Nataliia S.
Trush, Victor A.
Medviediev, Volodymyr V.
Sliva, Tetyana Yu.
Amirkhanov, Vladimir M.
author_sort Kariaka, Nataliia S.
collection PubMed
description In both independent mol­ecules of the title compound, [Nd(C(9)H(11)NO(4)P)(3)(C(12)H(8)N(2))], the Nd(III) atom is coordinated by six O atoms belonging to three phosphoryl ligands and two N atoms of 1,10-phenanthroline in a dodeca­hedral geometry. In the phosphoryl ligands, the benzene rings are twisted with respect to the planes of the sp (2)-hybridized C atoms of the chelate rings by 12.1 (1)–24.7 (1)°.
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spelling pubmed-35884352013-03-08 Tris[dimethyl (benzoyl­amido)­phosphato-κ(2) O,O′](1,10-phenanthroline-κ(2) N,N′)neodymium(III) Kariaka, Nataliia S. Trush, Victor A. Medviediev, Volodymyr V. Sliva, Tetyana Yu. Amirkhanov, Vladimir M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In both independent mol­ecules of the title compound, [Nd(C(9)H(11)NO(4)P)(3)(C(12)H(8)N(2))], the Nd(III) atom is coordinated by six O atoms belonging to three phosphoryl ligands and two N atoms of 1,10-phenanthroline in a dodeca­hedral geometry. In the phosphoryl ligands, the benzene rings are twisted with respect to the planes of the sp (2)-hybridized C atoms of the chelate rings by 12.1 (1)–24.7 (1)°. International Union of Crystallography 2013-02-09 /pmc/articles/PMC3588435/ /pubmed/23476491 http://dx.doi.org/10.1107/S1600536813003462 Text en © Kariaka et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kariaka, Nataliia S.
Trush, Victor A.
Medviediev, Volodymyr V.
Sliva, Tetyana Yu.
Amirkhanov, Vladimir M.
Tris[dimethyl (benzoyl­amido)­phosphato-κ(2) O,O′](1,10-phenanthroline-κ(2) N,N′)neodymium(III)
title Tris[dimethyl (benzoyl­amido)­phosphato-κ(2) O,O′](1,10-phenanthroline-κ(2) N,N′)neodymium(III)
title_full Tris[dimethyl (benzoyl­amido)­phosphato-κ(2) O,O′](1,10-phenanthroline-κ(2) N,N′)neodymium(III)
title_fullStr Tris[dimethyl (benzoyl­amido)­phosphato-κ(2) O,O′](1,10-phenanthroline-κ(2) N,N′)neodymium(III)
title_full_unstemmed Tris[dimethyl (benzoyl­amido)­phosphato-κ(2) O,O′](1,10-phenanthroline-κ(2) N,N′)neodymium(III)
title_short Tris[dimethyl (benzoyl­amido)­phosphato-κ(2) O,O′](1,10-phenanthroline-κ(2) N,N′)neodymium(III)
title_sort tris[dimethyl (benzoyl­amido)­phosphato-κ(2) o,o′](1,10-phenanthroline-κ(2) n,n′)neodymium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588435/
https://www.ncbi.nlm.nih.gov/pubmed/23476491
http://dx.doi.org/10.1107/S1600536813003462
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