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Tris[dimethyl (benzoylamido)phosphato-κ(2) O,O′](1,10-phenanthroline-κ(2) N,N′)neodymium(III)
In both independent molecules of the title compound, [Nd(C(9)H(11)NO(4)P)(3)(C(12)H(8)N(2))], the Nd(III) atom is coordinated by six O atoms belonging to three phosphoryl ligands and two N atoms of 1,10-phenanthroline in a dodecahedral geometry. In the phosphoryl ligands, the benzene rings are twi...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588435/ https://www.ncbi.nlm.nih.gov/pubmed/23476491 http://dx.doi.org/10.1107/S1600536813003462 |
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author | Kariaka, Nataliia S. Trush, Victor A. Medviediev, Volodymyr V. Sliva, Tetyana Yu. Amirkhanov, Vladimir M. |
author_facet | Kariaka, Nataliia S. Trush, Victor A. Medviediev, Volodymyr V. Sliva, Tetyana Yu. Amirkhanov, Vladimir M. |
author_sort | Kariaka, Nataliia S. |
collection | PubMed |
description | In both independent molecules of the title compound, [Nd(C(9)H(11)NO(4)P)(3)(C(12)H(8)N(2))], the Nd(III) atom is coordinated by six O atoms belonging to three phosphoryl ligands and two N atoms of 1,10-phenanthroline in a dodecahedral geometry. In the phosphoryl ligands, the benzene rings are twisted with respect to the planes of the sp (2)-hybridized C atoms of the chelate rings by 12.1 (1)–24.7 (1)°. |
format | Online Article Text |
id | pubmed-3588435 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35884352013-03-08 Tris[dimethyl (benzoylamido)phosphato-κ(2) O,O′](1,10-phenanthroline-κ(2) N,N′)neodymium(III) Kariaka, Nataliia S. Trush, Victor A. Medviediev, Volodymyr V. Sliva, Tetyana Yu. Amirkhanov, Vladimir M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In both independent molecules of the title compound, [Nd(C(9)H(11)NO(4)P)(3)(C(12)H(8)N(2))], the Nd(III) atom is coordinated by six O atoms belonging to three phosphoryl ligands and two N atoms of 1,10-phenanthroline in a dodecahedral geometry. In the phosphoryl ligands, the benzene rings are twisted with respect to the planes of the sp (2)-hybridized C atoms of the chelate rings by 12.1 (1)–24.7 (1)°. International Union of Crystallography 2013-02-09 /pmc/articles/PMC3588435/ /pubmed/23476491 http://dx.doi.org/10.1107/S1600536813003462 Text en © Kariaka et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kariaka, Nataliia S. Trush, Victor A. Medviediev, Volodymyr V. Sliva, Tetyana Yu. Amirkhanov, Vladimir M. Tris[dimethyl (benzoylamido)phosphato-κ(2) O,O′](1,10-phenanthroline-κ(2) N,N′)neodymium(III) |
title | Tris[dimethyl (benzoylamido)phosphato-κ(2)
O,O′](1,10-phenanthroline-κ(2)
N,N′)neodymium(III) |
title_full | Tris[dimethyl (benzoylamido)phosphato-κ(2)
O,O′](1,10-phenanthroline-κ(2)
N,N′)neodymium(III) |
title_fullStr | Tris[dimethyl (benzoylamido)phosphato-κ(2)
O,O′](1,10-phenanthroline-κ(2)
N,N′)neodymium(III) |
title_full_unstemmed | Tris[dimethyl (benzoylamido)phosphato-κ(2)
O,O′](1,10-phenanthroline-κ(2)
N,N′)neodymium(III) |
title_short | Tris[dimethyl (benzoylamido)phosphato-κ(2)
O,O′](1,10-phenanthroline-κ(2)
N,N′)neodymium(III) |
title_sort | tris[dimethyl (benzoylamido)phosphato-κ(2)
o,o′](1,10-phenanthroline-κ(2)
n,n′)neodymium(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588435/ https://www.ncbi.nlm.nih.gov/pubmed/23476491 http://dx.doi.org/10.1107/S1600536813003462 |
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