1-Allyl-5-nitro-1H-benzimidazol-2(3H)-one

The benzimidazolone residue in the title mol­ecule, C(10)H(9)N(3)O(3), is almost planar, with the largest deviation from the mean plane being 0.016 (2) Å for the C atom linked to the nitro group. This plane is nearly perpendicular to the 1-allyl chain as indicated by the C—N—C—C torsion angle of 90....

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Detalles Bibliográficos
Autores principales: Ouzidan, Younès, Kandri Rodi, Youssef, Kandri Rodi, Adiba, Essassi, El Mokhtar, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588436/
https://www.ncbi.nlm.nih.gov/pubmed/23476602
http://dx.doi.org/10.1107/S1600536813004790
Descripción
Sumario:The benzimidazolone residue in the title mol­ecule, C(10)H(9)N(3)O(3), is almost planar, with the largest deviation from the mean plane being 0.016 (2) Å for the C atom linked to the nitro group. This plane is nearly perpendicular to the 1-allyl chain as indicated by the C—N—C—C torsion angle of 90.9 (3)°. The fused-ring system makes a dihedral angle of 5.6 (3)° with the nitro group, leading to a synperiplanar conformation. In the crystal, zigzag supra­molecular chains are formed along the a axis by N—H⋯O hydrogen bonds.

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