1-Allyl-5-nitro-1H-benzimidazol-2(3H)-one

The benzimidazolone residue in the title mol­ecule, C(10)H(9)N(3)O(3), is almost planar, with the largest deviation from the mean plane being 0.016 (2) Å for the C atom linked to the nitro group. This plane is nearly perpendicular to the 1-allyl chain as indicated by the C—N—C—C torsion angle of 90....

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Autores principales: Ouzidan, Younès, Kandri Rodi, Youssef, Kandri Rodi, Adiba, Essassi, El Mokhtar, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588436/
https://www.ncbi.nlm.nih.gov/pubmed/23476602
http://dx.doi.org/10.1107/S1600536813004790
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author Ouzidan, Younès
Kandri Rodi, Youssef
Kandri Rodi, Adiba
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
author_facet Ouzidan, Younès
Kandri Rodi, Youssef
Kandri Rodi, Adiba
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
author_sort Ouzidan, Younès
collection PubMed
description The benzimidazolone residue in the title mol­ecule, C(10)H(9)N(3)O(3), is almost planar, with the largest deviation from the mean plane being 0.016 (2) Å for the C atom linked to the nitro group. This plane is nearly perpendicular to the 1-allyl chain as indicated by the C—N—C—C torsion angle of 90.9 (3)°. The fused-ring system makes a dihedral angle of 5.6 (3)° with the nitro group, leading to a synperiplanar conformation. In the crystal, zigzag supra­molecular chains are formed along the a axis by N—H⋯O hydrogen bonds.
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spelling pubmed-35884362013-03-08 1-Allyl-5-nitro-1H-benzimidazol-2(3H)-one Ouzidan, Younès Kandri Rodi, Youssef Kandri Rodi, Adiba Essassi, El Mokhtar Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers The benzimidazolone residue in the title mol­ecule, C(10)H(9)N(3)O(3), is almost planar, with the largest deviation from the mean plane being 0.016 (2) Å for the C atom linked to the nitro group. This plane is nearly perpendicular to the 1-allyl chain as indicated by the C—N—C—C torsion angle of 90.9 (3)°. The fused-ring system makes a dihedral angle of 5.6 (3)° with the nitro group, leading to a synperiplanar conformation. In the crystal, zigzag supra­molecular chains are formed along the a axis by N—H⋯O hydrogen bonds. International Union of Crystallography 2013-02-23 /pmc/articles/PMC3588436/ /pubmed/23476602 http://dx.doi.org/10.1107/S1600536813004790 Text en © Ouzidan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ouzidan, Younès
Kandri Rodi, Youssef
Kandri Rodi, Adiba
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
1-Allyl-5-nitro-1H-benzimidazol-2(3H)-one
title 1-Allyl-5-nitro-1H-benzimidazol-2(3H)-one
title_full 1-Allyl-5-nitro-1H-benzimidazol-2(3H)-one
title_fullStr 1-Allyl-5-nitro-1H-benzimidazol-2(3H)-one
title_full_unstemmed 1-Allyl-5-nitro-1H-benzimidazol-2(3H)-one
title_short 1-Allyl-5-nitro-1H-benzimidazol-2(3H)-one
title_sort 1-allyl-5-nitro-1h-benzimidazol-2(3h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588436/
https://www.ncbi.nlm.nih.gov/pubmed/23476602
http://dx.doi.org/10.1107/S1600536813004790
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