The Mg member of the isotypic series MTe(6)O(13)

MgTe(6)O(13), magnesium hexa­tellurate(IV), is isotypic with the structures of divalent first-row transition metal analogues MTe(6)O(13) (M = Mn, Fe, Co, Ni and Zn). The asymmetric unit contains one Mg, two Te and five O atoms of which the Mg and one O atom lie on a threefold rotation axis. The stru...

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Detalles Bibliográficos
Autores principales: Shirkhanlou, Mahdi, Weil, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588438/
https://www.ncbi.nlm.nih.gov/pubmed/23476481
http://dx.doi.org/10.1107/S1600536813003875
Descripción
Sumario:MgTe(6)O(13), magnesium hexa­tellurate(IV), is isotypic with the structures of divalent first-row transition metal analogues MTe(6)O(13) (M = Mn, Fe, Co, Ni and Zn). The asymmetric unit contains one Mg, two Te and five O atoms of which the Mg and one O atom lie on a threefold rotation axis. The structure is made up from slightly distorted [MgO(6)] octa­hedra (isolated from each other), distorted [TeO(4)] bis­phenoids and [TeO(4 + 1)] tetra­gonal pyramids sharing corners and edges. This arrangement leads to the formation of a dense three-dimensional structure.

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