Bis(azido-κN)bis­[4-(dimethyl­amino)­pyridine-κN]zinc

In the title complex, [Zn(N(3))(2)(C(7)H(10)N(2))(2)], the Zn(II) atom is coordinated by two N atoms from two 4-(dimethyl­amino)­pyridine (DMAP) ligands and by two N atoms from two azide anions in a distorted tetra­hedral coordination geometry. In the crystal, weak C—H⋯N hydrogen bonds between the D...

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Detalles Bibliográficos
Autores principales: Guenifa, Fatiha, Hadjadj, Nasreddine, Zeghouan, Ouahida, Bendjeddou, Lamia, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588442/
https://www.ncbi.nlm.nih.gov/pubmed/23476510
http://dx.doi.org/10.1107/S1600536813004686
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author Guenifa, Fatiha
Hadjadj, Nasreddine
Zeghouan, Ouahida
Bendjeddou, Lamia
Merazig, Hocine
author_facet Guenifa, Fatiha
Hadjadj, Nasreddine
Zeghouan, Ouahida
Bendjeddou, Lamia
Merazig, Hocine
author_sort Guenifa, Fatiha
collection PubMed
description In the title complex, [Zn(N(3))(2)(C(7)H(10)N(2))(2)], the Zn(II) atom is coordinated by two N atoms from two 4-(dimethyl­amino)­pyridine (DMAP) ligands and by two N atoms from two azide anions in a distorted tetra­hedral coordination geometry. In the crystal, weak C—H⋯N hydrogen bonds between the DMAP and azide ligands link these discrete complex mol­ecules into a three-dimensional supra­molecular network.
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spelling pubmed-35884422013-03-08 Bis(azido-κN)bis­[4-(dimethyl­amino)­pyridine-κN]zinc Guenifa, Fatiha Hadjadj, Nasreddine Zeghouan, Ouahida Bendjeddou, Lamia Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(N(3))(2)(C(7)H(10)N(2))(2)], the Zn(II) atom is coordinated by two N atoms from two 4-(dimethyl­amino)­pyridine (DMAP) ligands and by two N atoms from two azide anions in a distorted tetra­hedral coordination geometry. In the crystal, weak C—H⋯N hydrogen bonds between the DMAP and azide ligands link these discrete complex mol­ecules into a three-dimensional supra­molecular network. International Union of Crystallography 2013-02-23 /pmc/articles/PMC3588442/ /pubmed/23476510 http://dx.doi.org/10.1107/S1600536813004686 Text en © Guenifa et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guenifa, Fatiha
Hadjadj, Nasreddine
Zeghouan, Ouahida
Bendjeddou, Lamia
Merazig, Hocine
Bis(azido-κN)bis­[4-(dimethyl­amino)­pyridine-κN]zinc
title Bis(azido-κN)bis­[4-(dimethyl­amino)­pyridine-κN]zinc
title_full Bis(azido-κN)bis­[4-(dimethyl­amino)­pyridine-κN]zinc
title_fullStr Bis(azido-κN)bis­[4-(dimethyl­amino)­pyridine-κN]zinc
title_full_unstemmed Bis(azido-κN)bis­[4-(dimethyl­amino)­pyridine-κN]zinc
title_short Bis(azido-κN)bis­[4-(dimethyl­amino)­pyridine-κN]zinc
title_sort bis(azido-κn)bis­[4-(dimethyl­amino)­pyridine-κn]zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588442/
https://www.ncbi.nlm.nih.gov/pubmed/23476510
http://dx.doi.org/10.1107/S1600536813004686
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