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N,N,N′,N′-Tetramethyl-N′′-[3-(trimethylazaniumyl)propyl]guanidinium bis(tetraphenylborate) acetone disolvate
In the title solvated salt, C(11)H(28)N(4) (2+)·2C(24)H(20)B(−)·2C(3)H(6)O, the C—N bond lengths in the central CN(3) unit of the guanidinium ion are 1.3331 (16), 1.3407 (16) and 1.3454 (16) Å, indicating partial double-bond character in each. The central C atom is bonded to the three N atoms in a n...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588446/ https://www.ncbi.nlm.nih.gov/pubmed/23476532 http://dx.doi.org/10.1107/S1600536813003024 |
Sumario: | In the title solvated salt, C(11)H(28)N(4) (2+)·2C(24)H(20)B(−)·2C(3)H(6)O, the C—N bond lengths in the central CN(3) unit of the guanidinium ion are 1.3331 (16), 1.3407 (16) and 1.3454 (16) Å, indicating partial double-bond character in each. The central C atom is bonded to the three N atoms in a nearly ideal trigonal–planar geometry [N—C—N angles = 118.96 (11), 120.51 (12) and 120.53 (11)°] and the positive charge is delocalized in the CN(3) plane. The bonds between the N atoms and the terminal C-methyl groups of the guanidinium moiety all have values close to a typical single bond [1.4601 (16)–1.4649 (16) Å]. In the crystal, the guanidinium ion is connected by N—H⋯O and C—H⋯O hydrogen bonds with the acetone molecules. C—H⋯π interactions are present between the guanidinium H atoms and the phenyl rings of both tetraphenylborate ions. The phenyl rings form aromatic pockets, in which the guanidinium ions are embedded. |
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