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3-Methyl­ideneoxolane-2,5-dione

The title compound (itaconic anhydride), C(5)H(4)O(3), consists of a five-membered carbon–oxygen ring in a flat envelope conformation (the unsubstituted C atom being the flap) with three exocyclic double bonds to two O atoms and one C atom. In contrast to the bond lengths, which are very similar to...

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Detalles Bibliográficos
Autores principales: Beginn, Uwe, Frosinn, Martin, Reichelt, Martin, Reuter, Hans
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588448/
https://www.ncbi.nlm.nih.gov/pubmed/23476519
http://dx.doi.org/10.1107/S1600536813002924
Descripción
Sumario:The title compound (itaconic anhydride), C(5)H(4)O(3), consists of a five-membered carbon–oxygen ring in a flat envelope conformation (the unsubstituted C atom being the flap) with three exocyclic double bonds to two O atoms and one C atom. In contrast to the bond lengths, which are very similar to those in itaconic acid in its pure form or in adducts with other mol­ecules, the bond angles differ significantly because of the effect of ring closure giving rise to strong distortions at the C atoms involved in the exocyclic double bonds. In the crystal, C—H⋯O inter­actions link the mol­ecules, forming an extended three-dimensional network.