Bis[2-(1H-benzotriazol-1-yl)-1H-benz­imidazol-1-ido]diethano­lcadmium

In the title complex, [Cd(C(13)H(8)N(5))(2)(C(2)H(5)OH)(2)], the Cd(II) cation is located on an inversion center and coordinated by two deprotonated 2-(1H-benzotriazol-1-yl)-1H-benzimid­azol-1-ide (L) ligands and two ethanol mol­ecules in a distorted N(4)O(2) octa­hedral geometry. In the L ligand, t...

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Detalles Bibliográficos
Autores principales: Cao, Ping, Liu, Jia-Cheng, Hu, Dong-Cheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588456/
https://www.ncbi.nlm.nih.gov/pubmed/23476484
http://dx.doi.org/10.1107/S1600536813001827
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author Cao, Ping
Liu, Jia-Cheng
Hu, Dong-Cheng
author_facet Cao, Ping
Liu, Jia-Cheng
Hu, Dong-Cheng
author_sort Cao, Ping
collection PubMed
description In the title complex, [Cd(C(13)H(8)N(5))(2)(C(2)H(5)OH)(2)], the Cd(II) cation is located on an inversion center and coordinated by two deprotonated 2-(1H-benzotriazol-1-yl)-1H-benzimid­azol-1-ide (L) ligands and two ethanol mol­ecules in a distorted N(4)O(2) octa­hedral geometry. In the L ligand, the dihedral angle between benzoimidazole and benzotriazole ring systems is 10.8 (3)°. In the crystal, the complex mol­ecules are connected by O—H⋯N hydrogen bonds; inter­molecular π–π stacking is also observed [centroid–centroid distances of 3.668 (5) Å between triazole and benzene rings and 3.780 (5) Å between imidazole rings].
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spelling pubmed-35884562013-03-08 Bis[2-(1H-benzotriazol-1-yl)-1H-benz­imidazol-1-ido]diethano­lcadmium Cao, Ping Liu, Jia-Cheng Hu, Dong-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(13)H(8)N(5))(2)(C(2)H(5)OH)(2)], the Cd(II) cation is located on an inversion center and coordinated by two deprotonated 2-(1H-benzotriazol-1-yl)-1H-benzimid­azol-1-ide (L) ligands and two ethanol mol­ecules in a distorted N(4)O(2) octa­hedral geometry. In the L ligand, the dihedral angle between benzoimidazole and benzotriazole ring systems is 10.8 (3)°. In the crystal, the complex mol­ecules are connected by O—H⋯N hydrogen bonds; inter­molecular π–π stacking is also observed [centroid–centroid distances of 3.668 (5) Å between triazole and benzene rings and 3.780 (5) Å between imidazole rings]. International Union of Crystallography 2013-02-02 /pmc/articles/PMC3588456/ /pubmed/23476484 http://dx.doi.org/10.1107/S1600536813001827 Text en © Cao et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cao, Ping
Liu, Jia-Cheng
Hu, Dong-Cheng
Bis[2-(1H-benzotriazol-1-yl)-1H-benz­imidazol-1-ido]diethano­lcadmium
title Bis[2-(1H-benzotriazol-1-yl)-1H-benz­imidazol-1-ido]diethano­lcadmium
title_full Bis[2-(1H-benzotriazol-1-yl)-1H-benz­imidazol-1-ido]diethano­lcadmium
title_fullStr Bis[2-(1H-benzotriazol-1-yl)-1H-benz­imidazol-1-ido]diethano­lcadmium
title_full_unstemmed Bis[2-(1H-benzotriazol-1-yl)-1H-benz­imidazol-1-ido]diethano­lcadmium
title_short Bis[2-(1H-benzotriazol-1-yl)-1H-benz­imidazol-1-ido]diethano­lcadmium
title_sort bis[2-(1h-benzotriazol-1-yl)-1h-benz­imidazol-1-ido]diethano­lcadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588456/
https://www.ncbi.nlm.nih.gov/pubmed/23476484
http://dx.doi.org/10.1107/S1600536813001827
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