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Diaqua­bis­(2-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)

In the title complex, [Co(C(7)H(4)ClO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) cation is located on an inversion center and is coord­inated by two 2-chloro­benzoate anions, two nicotin­amide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Co(II) cati...

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Autores principales: Dincel, Öznur, Tercan, Barış, Öztürkkan, Füreya Elif, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588457/
https://www.ncbi.nlm.nih.gov/pubmed/23476513
http://dx.doi.org/10.1107/S1600536813004984
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author Dincel, Öznur
Tercan, Barış
Öztürkkan, Füreya Elif
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Dincel, Öznur
Tercan, Barış
Öztürkkan, Füreya Elif
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Dincel, Öznur
collection PubMed
description In the title complex, [Co(C(7)H(4)ClO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) cation is located on an inversion center and is coord­inated by two 2-chloro­benzoate anions, two nicotin­amide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Co(II) cation form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 29.7 (4)°, while the pyridine and benzene rings are oriented at a dihedral angle of 83.17 (15)°. Intra­molecular O—H⋯O hydrogen bonding occurs between the carboxyl­ate group and coordinating water mol­ecule. In the crystal, inter­molecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network.
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spelling pubmed-35884572013-03-08 Diaqua­bis­(2-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II) Dincel, Öznur Tercan, Barış Öztürkkan, Füreya Elif Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(7)H(4)ClO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) cation is located on an inversion center and is coord­inated by two 2-chloro­benzoate anions, two nicotin­amide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Co(II) cation form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 29.7 (4)°, while the pyridine and benzene rings are oriented at a dihedral angle of 83.17 (15)°. Intra­molecular O—H⋯O hydrogen bonding occurs between the carboxyl­ate group and coordinating water mol­ecule. In the crystal, inter­molecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. International Union of Crystallography 2013-02-28 /pmc/articles/PMC3588457/ /pubmed/23476513 http://dx.doi.org/10.1107/S1600536813004984 Text en © Dincel et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dincel, Öznur
Tercan, Barış
Öztürkkan, Füreya Elif
Necefoğlu, Hacali
Hökelek, Tuncer
Diaqua­bis­(2-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title Diaqua­bis­(2-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_full Diaqua­bis­(2-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_fullStr Diaqua­bis­(2-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_full_unstemmed Diaqua­bis­(2-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_short Diaqua­bis­(2-chloro­benzoato-κO)bis­(nicotinamide-κN (1))cobalt(II)
title_sort diaqua­bis­(2-chloro­benzoato-κo)bis­(nicotinamide-κn (1))cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588457/
https://www.ncbi.nlm.nih.gov/pubmed/23476513
http://dx.doi.org/10.1107/S1600536813004984
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