Poly[tris­(dimethyl­formamide)(μ(3)-2,4,6-triiodobenzene-1,3,5-tricarboxyl­ato)samarium(III)]

In the title compound, [Sm(C(9)I(3)O(6))(C(3)H(7)NO)(3)](n), the Sm(III) atom is coordinated by nine O atoms, viz. six carboxyl­ate O atoms from three 2,4,6-triiodobenzene-1,3,5-tricarboxyl­ate (I(3)BTC) ligands and three O atoms from three N,N-dimethyl­formamide (DMF) mol­ecules. Each I(3)BTC ligan...

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Detalles Bibliográficos
Autores principales: Yan, Bin, Sheng, Daopeng, Yang, Yanzhao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588465/
https://www.ncbi.nlm.nih.gov/pubmed/23476496
http://dx.doi.org/10.1107/S1600536813003358
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author Yan, Bin
Sheng, Daopeng
Yang, Yanzhao
author_facet Yan, Bin
Sheng, Daopeng
Yang, Yanzhao
author_sort Yan, Bin
collection PubMed
description In the title compound, [Sm(C(9)I(3)O(6))(C(3)H(7)NO)(3)](n), the Sm(III) atom is coordinated by nine O atoms, viz. six carboxyl­ate O atoms from three 2,4,6-triiodobenzene-1,3,5-tricarboxyl­ate (I(3)BTC) ligands and three O atoms from three N,N-dimethyl­formamide (DMF) mol­ecules. Each I(3)BTC ligand bridges three Sm(III) atoms, generating a three-dimensional metal-organic framework structure. The asymmetric unit contains one Sm(III) ion and one I(3)BTC anion, both situated on a threefold axis, and one DMF mol­ecule in a general position.
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spelling pubmed-35884652013-03-08 Poly[tris­(dimethyl­formamide)(μ(3)-2,4,6-triiodobenzene-1,3,5-tricarboxyl­ato)samarium(III)] Yan, Bin Sheng, Daopeng Yang, Yanzhao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sm(C(9)I(3)O(6))(C(3)H(7)NO)(3)](n), the Sm(III) atom is coordinated by nine O atoms, viz. six carboxyl­ate O atoms from three 2,4,6-triiodobenzene-1,3,5-tricarboxyl­ate (I(3)BTC) ligands and three O atoms from three N,N-dimethyl­formamide (DMF) mol­ecules. Each I(3)BTC ligand bridges three Sm(III) atoms, generating a three-dimensional metal-organic framework structure. The asymmetric unit contains one Sm(III) ion and one I(3)BTC anion, both situated on a threefold axis, and one DMF mol­ecule in a general position. International Union of Crystallography 2013-02-13 /pmc/articles/PMC3588465/ /pubmed/23476496 http://dx.doi.org/10.1107/S1600536813003358 Text en © Yan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yan, Bin
Sheng, Daopeng
Yang, Yanzhao
Poly[tris­(dimethyl­formamide)(μ(3)-2,4,6-triiodobenzene-1,3,5-tricarboxyl­ato)samarium(III)]
title Poly[tris­(dimethyl­formamide)(μ(3)-2,4,6-triiodobenzene-1,3,5-tricarboxyl­ato)samarium(III)]
title_full Poly[tris­(dimethyl­formamide)(μ(3)-2,4,6-triiodobenzene-1,3,5-tricarboxyl­ato)samarium(III)]
title_fullStr Poly[tris­(dimethyl­formamide)(μ(3)-2,4,6-triiodobenzene-1,3,5-tricarboxyl­ato)samarium(III)]
title_full_unstemmed Poly[tris­(dimethyl­formamide)(μ(3)-2,4,6-triiodobenzene-1,3,5-tricarboxyl­ato)samarium(III)]
title_short Poly[tris­(dimethyl­formamide)(μ(3)-2,4,6-triiodobenzene-1,3,5-tricarboxyl­ato)samarium(III)]
title_sort poly[tris­(dimethyl­formamide)(μ(3)-2,4,6-triiodobenzene-1,3,5-tricarboxyl­ato)samarium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588465/
https://www.ncbi.nlm.nih.gov/pubmed/23476496
http://dx.doi.org/10.1107/S1600536813003358
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