2-[3-Meth­oxy-5-(pyrimidin-2-yl)phen­yl]pyrimidine

The title compound, C(15)H(12)N(4)O, was synthesized by a standard Suzuki cross-coupling reaction. The terminal pyrim­idine rings are rotated at dihedral angles of 12.06 (4) and −13.13 (4)° with respect to the central benzene ring. In the crystal, the mol­ecules are connected by two kinds of C—H⋯N h...

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Detalles Bibliográficos
Autores principales: Hu, Jiena, Wu, Yang, Zhang, Dengqing, Li, Xianying, Jin, Wusong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588471/
https://www.ncbi.nlm.nih.gov/pubmed/23476528
http://dx.doi.org/10.1107/S1600536813002663
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author Hu, Jiena
Wu, Yang
Zhang, Dengqing
Li, Xianying
Jin, Wusong
author_facet Hu, Jiena
Wu, Yang
Zhang, Dengqing
Li, Xianying
Jin, Wusong
author_sort Hu, Jiena
collection PubMed
description The title compound, C(15)H(12)N(4)O, was synthesized by a standard Suzuki cross-coupling reaction. The terminal pyrim­idine rings are rotated at dihedral angles of 12.06 (4) and −13.13 (4)° with respect to the central benzene ring. In the crystal, the mol­ecules are connected by two kinds of C—H⋯N hydrogen bonds, forming zigzag chains along the c axis. Weak π–π inter­actions between the benzene and one of the pyrimidine rings are also found and stack the mol­ecules along the b axis [centroid–centroid distance = 4.112 (3) Å].
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spelling pubmed-35884712013-03-08 2-[3-Meth­oxy-5-(pyrimidin-2-yl)phen­yl]pyrimidine Hu, Jiena Wu, Yang Zhang, Dengqing Li, Xianying Jin, Wusong Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)N(4)O, was synthesized by a standard Suzuki cross-coupling reaction. The terminal pyrim­idine rings are rotated at dihedral angles of 12.06 (4) and −13.13 (4)° with respect to the central benzene ring. In the crystal, the mol­ecules are connected by two kinds of C—H⋯N hydrogen bonds, forming zigzag chains along the c axis. Weak π–π inter­actions between the benzene and one of the pyrimidine rings are also found and stack the mol­ecules along the b axis [centroid–centroid distance = 4.112 (3) Å]. International Union of Crystallography 2013-02-02 /pmc/articles/PMC3588471/ /pubmed/23476528 http://dx.doi.org/10.1107/S1600536813002663 Text en © Hu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hu, Jiena
Wu, Yang
Zhang, Dengqing
Li, Xianying
Jin, Wusong
2-[3-Meth­oxy-5-(pyrimidin-2-yl)phen­yl]pyrimidine
title 2-[3-Meth­oxy-5-(pyrimidin-2-yl)phen­yl]pyrimidine
title_full 2-[3-Meth­oxy-5-(pyrimidin-2-yl)phen­yl]pyrimidine
title_fullStr 2-[3-Meth­oxy-5-(pyrimidin-2-yl)phen­yl]pyrimidine
title_full_unstemmed 2-[3-Meth­oxy-5-(pyrimidin-2-yl)phen­yl]pyrimidine
title_short 2-[3-Meth­oxy-5-(pyrimidin-2-yl)phen­yl]pyrimidine
title_sort 2-[3-meth­oxy-5-(pyrimidin-2-yl)phen­yl]pyrimidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588471/
https://www.ncbi.nlm.nih.gov/pubmed/23476528
http://dx.doi.org/10.1107/S1600536813002663
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AT wuyang 23methoxy5pyrimidin2ylphenylpyrimidine
AT zhangdengqing 23methoxy5pyrimidin2ylphenylpyrimidine
AT lixianying 23methoxy5pyrimidin2ylphenylpyrimidine
AT jinwusong 23methoxy5pyrimidin2ylphenylpyrimidine

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