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Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II)

In the title compound, [Mn(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Mn(II) ion is located on a twofold rotation axis and displays a distorted octa­hedral coordination environment, defined by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands in the equatorial plane and two water mol­ecules in axial p...

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Detalles Bibliográficos
Autores principales: Xiong, Zhi-Yong, Li, Lin, Zhao, Xiang-Jie, Chen, Hai-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588475/
https://www.ncbi.nlm.nih.gov/pubmed/23476512
http://dx.doi.org/10.1107/S1600536813004091
Descripción
Sumario:In the title compound, [Mn(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Mn(II) ion is located on a twofold rotation axis and displays a distorted octa­hedral coordination environment, defined by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands in the equatorial plane and two water mol­ecules in axial positions. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. π–π stacking inter­actions between the imidazole rings [centroid–centroid distances = 3.5188 (15) and 3.6687 (15) Å] further stabilize the structure.