Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II)

In the title compound, [Mn(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Mn(II) ion is located on a twofold rotation axis and displays a distorted octa­hedral coordination environment, defined by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands in the equatorial plane and two water mol­ecules in axial p...

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Detalles Bibliográficos
Autores principales: Xiong, Zhi-Yong, Li, Lin, Zhao, Xiang-Jie, Chen, Hai-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588475/
https://www.ncbi.nlm.nih.gov/pubmed/23476512
http://dx.doi.org/10.1107/S1600536813004091
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author Xiong, Zhi-Yong
Li, Lin
Zhao, Xiang-Jie
Chen, Hai-Ming
author_facet Xiong, Zhi-Yong
Li, Lin
Zhao, Xiang-Jie
Chen, Hai-Ming
author_sort Xiong, Zhi-Yong
collection PubMed
description In the title compound, [Mn(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Mn(II) ion is located on a twofold rotation axis and displays a distorted octa­hedral coordination environment, defined by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands in the equatorial plane and two water mol­ecules in axial positions. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. π–π stacking inter­actions between the imidazole rings [centroid–centroid distances = 3.5188 (15) and 3.6687 (15) Å] further stabilize the structure.
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spelling pubmed-35884752013-03-08 Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II) Xiong, Zhi-Yong Li, Lin Zhao, Xiang-Jie Chen, Hai-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Mn(II) ion is located on a twofold rotation axis and displays a distorted octa­hedral coordination environment, defined by two N,O-bidentate 1H-imidazole-4-carboxyl­ate ligands in the equatorial plane and two water mol­ecules in axial positions. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. π–π stacking inter­actions between the imidazole rings [centroid–centroid distances = 3.5188 (15) and 3.6687 (15) Å] further stabilize the structure. International Union of Crystallography 2013-02-28 /pmc/articles/PMC3588475/ /pubmed/23476512 http://dx.doi.org/10.1107/S1600536813004091 Text en © Xiong et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xiong, Zhi-Yong
Li, Lin
Zhao, Xiang-Jie
Chen, Hai-Ming
Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II)
title Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II)
title_full Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II)
title_fullStr Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II)
title_full_unstemmed Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II)
title_short Diaqua­bis­(1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))manganese(II)
title_sort diaqua­bis­(1h-imidazole-4-carboxyl­ato-κ(2) n (3),o (4))manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588475/
https://www.ncbi.nlm.nih.gov/pubmed/23476512
http://dx.doi.org/10.1107/S1600536813004091
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