2-[(1H-Benzimidazol-2-yl)imino­meth­yl]-4,6-dibromo­phenol ethanol hemisolvate

The title compound, C(14)H(9)Br(2)N(3)O·0.5C(2)H(5)OH, crystallizes with two 2-[(1H-benzimidazol-2-yl)imino­meth­yl]-4,6-dibromo­phenol mol­ecules and one ethanol solvent mol­ecule in the asymmetric unit. The benzene and benzimidazole rings subtend dihedral angles of 4.5 (3) and 5.2 (2)° in the two...

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Detalles Bibliográficos
Autores principales: Liu, Jie, Liu, Zheng, Yuan, Shuai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588477/
https://www.ncbi.nlm.nih.gov/pubmed/23476552
http://dx.doi.org/10.1107/S1600536813002031
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author Liu, Jie
Liu, Zheng
Yuan, Shuai
author_facet Liu, Jie
Liu, Zheng
Yuan, Shuai
author_sort Liu, Jie
collection PubMed
description The title compound, C(14)H(9)Br(2)N(3)O·0.5C(2)H(5)OH, crystallizes with two 2-[(1H-benzimidazol-2-yl)imino­meth­yl]-4,6-dibromo­phenol mol­ecules and one ethanol solvent mol­ecule in the asymmetric unit. The benzene and benzimidazole rings subtend dihedral angles of 4.5 (3) and 5.2 (2)° in the two mol­ecules. In the crystal, one mol­ecule presents π–π stacking with the equivalent mol­ecule related by inversion, at a distance of 3.30 Å (separation between mol­ecular mean planes). A three-dimensional network is formed through N—H⋯N, N—H⋯O and O—H⋯N hydrogen bonds.
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spelling pubmed-35884772013-03-08 2-[(1H-Benzimidazol-2-yl)imino­meth­yl]-4,6-dibromo­phenol ethanol hemisolvate Liu, Jie Liu, Zheng Yuan, Shuai Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(9)Br(2)N(3)O·0.5C(2)H(5)OH, crystallizes with two 2-[(1H-benzimidazol-2-yl)imino­meth­yl]-4,6-dibromo­phenol mol­ecules and one ethanol solvent mol­ecule in the asymmetric unit. The benzene and benzimidazole rings subtend dihedral angles of 4.5 (3) and 5.2 (2)° in the two mol­ecules. In the crystal, one mol­ecule presents π–π stacking with the equivalent mol­ecule related by inversion, at a distance of 3.30 Å (separation between mol­ecular mean planes). A three-dimensional network is formed through N—H⋯N, N—H⋯O and O—H⋯N hydrogen bonds. International Union of Crystallography 2013-02-09 /pmc/articles/PMC3588477/ /pubmed/23476552 http://dx.doi.org/10.1107/S1600536813002031 Text en © Liu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Jie
Liu, Zheng
Yuan, Shuai
2-[(1H-Benzimidazol-2-yl)imino­meth­yl]-4,6-dibromo­phenol ethanol hemisolvate
title 2-[(1H-Benzimidazol-2-yl)imino­meth­yl]-4,6-dibromo­phenol ethanol hemisolvate
title_full 2-[(1H-Benzimidazol-2-yl)imino­meth­yl]-4,6-dibromo­phenol ethanol hemisolvate
title_fullStr 2-[(1H-Benzimidazol-2-yl)imino­meth­yl]-4,6-dibromo­phenol ethanol hemisolvate
title_full_unstemmed 2-[(1H-Benzimidazol-2-yl)imino­meth­yl]-4,6-dibromo­phenol ethanol hemisolvate
title_short 2-[(1H-Benzimidazol-2-yl)imino­meth­yl]-4,6-dibromo­phenol ethanol hemisolvate
title_sort 2-[(1h-benzimidazol-2-yl)imino­meth­yl]-4,6-dibromo­phenol ethanol hemisolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588477/
https://www.ncbi.nlm.nih.gov/pubmed/23476552
http://dx.doi.org/10.1107/S1600536813002031
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