Cargando…
Poly[bis(1,3-dimethylimidazolidin-2-one)(μ(2)-2,5-dioxidoterephthalato)zirconium(IV)]
In the title coordination polymer, [Zr(C(8)H(2)O(6))(C(5)H(10)N(2)O)(2)](n), the Zr(IV) atom (site symmetry 2) is coordinated by two O,O′-bidentate 2,5-dioxidoterephthalate (DHTP(4−)) ligands and two O-bonded 1,3-dimethyl-2-imidazolidinone (DMI) ligands (the latter in a cis orientation) in a distort...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588485/ https://www.ncbi.nlm.nih.gov/pubmed/23476498 http://dx.doi.org/10.1107/S1600536813003449 |
Sumario: | In the title coordination polymer, [Zr(C(8)H(2)O(6))(C(5)H(10)N(2)O)(2)](n), the Zr(IV) atom (site symmetry 2) is coordinated by two O,O′-bidentate 2,5-dioxidoterephthalate (DHTP(4−)) ligands and two O-bonded 1,3-dimethyl-2-imidazolidinone (DMI) ligands (the latter in a cis orientation) in a distorted ZrO(6) octahedral geometry. The deprotonated hydroxy and carboxy O atoms of the DHTP(4−) ligand chelate the Zr(IV) ion via a six-membered ring; the dihedral angle between the carboxylate group and the aromatic ring is 14.46 (11)°. The DHTP(4−) ligand is completed by crystallographic inversion symmetry and coordinates to two Zr(IV) atoms, thereby forming polymeric zigzag chains propagating in [001]. |
---|