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Poly[bis­(1,3-dimethyl­imidazolidin-2-one)(μ(2)-2,5-dioxidoterephthalato)zirconium(IV)]

In the title coordination polymer, [Zr(C(8)H(2)O(6))(C(5)H(10)N(2)O)(2)](n), the Zr(IV) atom (site symmetry 2) is coordinated by two O,O′-bidentate 2,5-dioxidoterephthalate (DHTP(4−)) ligands and two O-bonded 1,3-dimethyl-2-imidazolidinone (DMI) ligands (the latter in a cis orientation) in a distort...

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Autores principales: Maercz, Matthias, Wragg, David Stephen, Dietzel, Pascal Daniel Croumbie, Fjellvåg, Helmer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588485/
https://www.ncbi.nlm.nih.gov/pubmed/23476498
http://dx.doi.org/10.1107/S1600536813003449
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author Maercz, Matthias
Wragg, David Stephen
Dietzel, Pascal Daniel Croumbie
Fjellvåg, Helmer
author_facet Maercz, Matthias
Wragg, David Stephen
Dietzel, Pascal Daniel Croumbie
Fjellvåg, Helmer
author_sort Maercz, Matthias
collection PubMed
description In the title coordination polymer, [Zr(C(8)H(2)O(6))(C(5)H(10)N(2)O)(2)](n), the Zr(IV) atom (site symmetry 2) is coordinated by two O,O′-bidentate 2,5-dioxidoterephthalate (DHTP(4−)) ligands and two O-bonded 1,3-dimethyl-2-imidazolidinone (DMI) ligands (the latter in a cis orientation) in a distorted ZrO(6) octa­hedral geometry. The deprotonated hy­droxy and carb­oxy O atoms of the DHTP(4−) ligand chelate the Zr(IV) ion via a six-membered ring; the dihedral angle between the carboxyl­ate group and the aromatic ring is 14.46 (11)°. The DHTP(4−) ligand is completed by crystallographic inversion symmetry and coordinates to two Zr(IV) atoms, thereby forming polymeric zigzag chains propagating in [001].
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spelling pubmed-35884852013-03-08 Poly[bis­(1,3-dimethyl­imidazolidin-2-one)(μ(2)-2,5-dioxidoterephthalato)zirconium(IV)] Maercz, Matthias Wragg, David Stephen Dietzel, Pascal Daniel Croumbie Fjellvåg, Helmer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Zr(C(8)H(2)O(6))(C(5)H(10)N(2)O)(2)](n), the Zr(IV) atom (site symmetry 2) is coordinated by two O,O′-bidentate 2,5-dioxidoterephthalate (DHTP(4−)) ligands and two O-bonded 1,3-dimethyl-2-imidazolidinone (DMI) ligands (the latter in a cis orientation) in a distorted ZrO(6) octa­hedral geometry. The deprotonated hy­droxy and carb­oxy O atoms of the DHTP(4−) ligand chelate the Zr(IV) ion via a six-membered ring; the dihedral angle between the carboxyl­ate group and the aromatic ring is 14.46 (11)°. The DHTP(4−) ligand is completed by crystallographic inversion symmetry and coordinates to two Zr(IV) atoms, thereby forming polymeric zigzag chains propagating in [001]. International Union of Crystallography 2013-02-16 /pmc/articles/PMC3588485/ /pubmed/23476498 http://dx.doi.org/10.1107/S1600536813003449 Text en © Maercz et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Maercz, Matthias
Wragg, David Stephen
Dietzel, Pascal Daniel Croumbie
Fjellvåg, Helmer
Poly[bis­(1,3-dimethyl­imidazolidin-2-one)(μ(2)-2,5-dioxidoterephthalato)zirconium(IV)]
title Poly[bis­(1,3-dimethyl­imidazolidin-2-one)(μ(2)-2,5-dioxidoterephthalato)zirconium(IV)]
title_full Poly[bis­(1,3-dimethyl­imidazolidin-2-one)(μ(2)-2,5-dioxidoterephthalato)zirconium(IV)]
title_fullStr Poly[bis­(1,3-dimethyl­imidazolidin-2-one)(μ(2)-2,5-dioxidoterephthalato)zirconium(IV)]
title_full_unstemmed Poly[bis­(1,3-dimethyl­imidazolidin-2-one)(μ(2)-2,5-dioxidoterephthalato)zirconium(IV)]
title_short Poly[bis­(1,3-dimethyl­imidazolidin-2-one)(μ(2)-2,5-dioxidoterephthalato)zirconium(IV)]
title_sort poly[bis­(1,3-dimethyl­imidazolidin-2-one)(μ(2)-2,5-dioxidoterephthalato)zirconium(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588485/
https://www.ncbi.nlm.nih.gov/pubmed/23476498
http://dx.doi.org/10.1107/S1600536813003449
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