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Di-μ(2)-chlorido-bis­[chlorido(η(5)-2,3,4,5-tetra­methyl-1-propyl­cyclo­penta­dien­yl)iridium(III)]

The asymmetric unit of the title complex, [Ir(2)Cl(4)(C(12)H(19))(2)], a versatile starting material for the preparation of uniquely substituted penta­alkyl­cyclo­penta­dien­yl–iridium complexes, consists of an iridium(III) atom, a substituted cyclo­penta­dienyl ligand and two chlorine ligands. The...

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Detalles Bibliográficos
Autores principales: Merola, Joseph S., Morris, David, De Weerd, Nicholas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588487/
https://www.ncbi.nlm.nih.gov/pubmed/23476515
http://dx.doi.org/10.1107/S1600536813005072
Descripción
Sumario:The asymmetric unit of the title complex, [Ir(2)Cl(4)(C(12)H(19))(2)], a versatile starting material for the preparation of uniquely substituted penta­alkyl­cyclo­penta­dien­yl–iridium complexes, consists of an iridium(III) atom, a substituted cyclo­penta­dienyl ligand and two chlorine ligands. The full dimer is generated by an inversion center. In the dimer, the two Ir(III) atoms and two bridging Cl atoms form a perfectly planar ring. The two Ir(III) atoms and the two terminal Cl atoms also form a rigorous plane that is orthogonal [89.48 (3)°] to the Ir(2)Cl(2) ring. The plane of the cyclo­penta­dienyl ligand forms a dihedral angle of 54.06 (7)° with respect to the Ir(2)Cl(2) ring.