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Di-μ(2)-chlorido-bis[chlorido(η(5)-2,3,4,5-tetramethyl-1-propylcyclopentadienyl)iridium(III)]
The asymmetric unit of the title complex, [Ir(2)Cl(4)(C(12)H(19))(2)], a versatile starting material for the preparation of uniquely substituted pentaalkylcyclopentadienyl–iridium complexes, consists of an iridium(III) atom, a substituted cyclopentadienyl ligand and two chlorine ligands. The...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588487/ https://www.ncbi.nlm.nih.gov/pubmed/23476515 http://dx.doi.org/10.1107/S1600536813005072 |
Sumario: | The asymmetric unit of the title complex, [Ir(2)Cl(4)(C(12)H(19))(2)], a versatile starting material for the preparation of uniquely substituted pentaalkylcyclopentadienyl–iridium complexes, consists of an iridium(III) atom, a substituted cyclopentadienyl ligand and two chlorine ligands. The full dimer is generated by an inversion center. In the dimer, the two Ir(III) atoms and two bridging Cl atoms form a perfectly planar ring. The two Ir(III) atoms and the two terminal Cl atoms also form a rigorous plane that is orthogonal [89.48 (3)°] to the Ir(2)Cl(2) ring. The plane of the cyclopentadienyl ligand forms a dihedral angle of 54.06 (7)° with respect to the Ir(2)Cl(2) ring. |
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