Bis[(E)-3-(4-meth­oxy­phen­yl)prop-2-enoato]triphenyl­anti­mony(V) benzene monosolvate

The asymmetric unit of the title compound, [Sb(C(6)H(5))(3)(C(10)H(9)O(3))(2)]·C(6)H(6), contains one organometallic mol­ecule and one benzene mol­ecule that is disordered over two sets of sites with an occupancy ratio of 0.556 (15):0.444 (15). The Sb(V) atom is in a distorted trigonal–bipyramidal e...

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Detalles Bibliográficos
Autores principales: Andreev, Pavel V., Somov, Nikolay V., Kalistratova, Olga S., Gushchin, Alexey V., Chuprunov, Evgeny V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588489/
https://www.ncbi.nlm.nih.gov/pubmed/23476508
http://dx.doi.org/10.1107/S1600536813004674
Descripción
Sumario:The asymmetric unit of the title compound, [Sb(C(6)H(5))(3)(C(10)H(9)O(3))(2)]·C(6)H(6), contains one organometallic mol­ecule and one benzene mol­ecule that is disordered over two sets of sites with an occupancy ratio of 0.556 (15):0.444 (15). The Sb(V) atom is in a distorted trigonal–bipyramidal environment with the carboxyl­ate O atoms in axial positions and phenyl C atoms in the equatorial plane. As a result of additional Sb⋯O inter­actions, one of the C—Sb—C angles is widened to 140.19 (6)°.

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