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Bis[(E)-3-(4-methoxyphenyl)prop-2-enoato]triphenylantimony(V) benzene monosolvate
The asymmetric unit of the title compound, [Sb(C(6)H(5))(3)(C(10)H(9)O(3))(2)]·C(6)H(6), contains one organometallic molecule and one benzene molecule that is disordered over two sets of sites with an occupancy ratio of 0.556 (15):0.444 (15). The Sb(V) atom is in a distorted trigonal–bipyramidal e...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588489/ https://www.ncbi.nlm.nih.gov/pubmed/23476508 http://dx.doi.org/10.1107/S1600536813004674 |
| _version_ | 1782261577479618560 |
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| author | Andreev, Pavel V. Somov, Nikolay V. Kalistratova, Olga S. Gushchin, Alexey V. Chuprunov, Evgeny V. |
| author_facet | Andreev, Pavel V. Somov, Nikolay V. Kalistratova, Olga S. Gushchin, Alexey V. Chuprunov, Evgeny V. |
| author_sort | Andreev, Pavel V. |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Sb(C(6)H(5))(3)(C(10)H(9)O(3))(2)]·C(6)H(6), contains one organometallic molecule and one benzene molecule that is disordered over two sets of sites with an occupancy ratio of 0.556 (15):0.444 (15). The Sb(V) atom is in a distorted trigonal–bipyramidal environment with the carboxylate O atoms in axial positions and phenyl C atoms in the equatorial plane. As a result of additional Sb⋯O interactions, one of the C—Sb—C angles is widened to 140.19 (6)°. |
| format | Online Article Text |
| id | pubmed-3588489 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35884892013-03-08 Bis[(E)-3-(4-methoxyphenyl)prop-2-enoato]triphenylantimony(V) benzene monosolvate Andreev, Pavel V. Somov, Nikolay V. Kalistratova, Olga S. Gushchin, Alexey V. Chuprunov, Evgeny V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Sb(C(6)H(5))(3)(C(10)H(9)O(3))(2)]·C(6)H(6), contains one organometallic molecule and one benzene molecule that is disordered over two sets of sites with an occupancy ratio of 0.556 (15):0.444 (15). The Sb(V) atom is in a distorted trigonal–bipyramidal environment with the carboxylate O atoms in axial positions and phenyl C atoms in the equatorial plane. As a result of additional Sb⋯O interactions, one of the C—Sb—C angles is widened to 140.19 (6)°. International Union of Crystallography 2013-02-23 /pmc/articles/PMC3588489/ /pubmed/23476508 http://dx.doi.org/10.1107/S1600536813004674 Text en © Andreev et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Andreev, Pavel V. Somov, Nikolay V. Kalistratova, Olga S. Gushchin, Alexey V. Chuprunov, Evgeny V. Bis[(E)-3-(4-methoxyphenyl)prop-2-enoato]triphenylantimony(V) benzene monosolvate |
| title | Bis[(E)-3-(4-methoxyphenyl)prop-2-enoato]triphenylantimony(V) benzene monosolvate |
| title_full | Bis[(E)-3-(4-methoxyphenyl)prop-2-enoato]triphenylantimony(V) benzene monosolvate |
| title_fullStr | Bis[(E)-3-(4-methoxyphenyl)prop-2-enoato]triphenylantimony(V) benzene monosolvate |
| title_full_unstemmed | Bis[(E)-3-(4-methoxyphenyl)prop-2-enoato]triphenylantimony(V) benzene monosolvate |
| title_short | Bis[(E)-3-(4-methoxyphenyl)prop-2-enoato]triphenylantimony(V) benzene monosolvate |
| title_sort | bis[(e)-3-(4-methoxyphenyl)prop-2-enoato]triphenylantimony(v) benzene monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588489/ https://www.ncbi.nlm.nih.gov/pubmed/23476508 http://dx.doi.org/10.1107/S1600536813004674 |
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