Bis{2-bromo-4-chloro-6-[(E)-(2,6-di­methyl­phen­yl)imino­meth­yl]phenolato-κ(2) N,O}cobalt(II)

In the title complex, [Co(C(15)H(12)BrClNO)(2)], the Co(II) ion is coordinated by two N,O-bidentate 2-bromo-4-chloro-6-[(E)-(2,6-dimethyl­phen­yl)imino­meth­yl]phenolate ligands, generating a squashed CoN(2)O(2) tetra­hedral coordination geometry. The dihedral angles between the aromatic rings in th...

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Detalles Bibliográficos
Autores principales: Zhu, Gang, Jiao, Bao-Juan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588491/
https://www.ncbi.nlm.nih.gov/pubmed/23476501
http://dx.doi.org/10.1107/S1600536813003747
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author Zhu, Gang
Jiao, Bao-Juan
author_facet Zhu, Gang
Jiao, Bao-Juan
author_sort Zhu, Gang
collection PubMed
description In the title complex, [Co(C(15)H(12)BrClNO)(2)], the Co(II) ion is coordinated by two N,O-bidentate 2-bromo-4-chloro-6-[(E)-(2,6-dimethyl­phen­yl)imino­meth­yl]phenolate ligands, generating a squashed CoN(2)O(2) tetra­hedral coordination geometry. The dihedral angles between the aromatic rings in the ligands are 82.60 (14) and 71.79 (14)°. The complex has approximate local noncrystallographic twofold symmetry. In the crystal, weak aromatic π–π stacking is observed [centroid–centroid separation = 3.6434 (18) Å].
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spelling pubmed-35884912013-03-08 Bis{2-bromo-4-chloro-6-[(E)-(2,6-di­methyl­phen­yl)imino­meth­yl]phenolato-κ(2) N,O}cobalt(II) Zhu, Gang Jiao, Bao-Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(15)H(12)BrClNO)(2)], the Co(II) ion is coordinated by two N,O-bidentate 2-bromo-4-chloro-6-[(E)-(2,6-dimethyl­phen­yl)imino­meth­yl]phenolate ligands, generating a squashed CoN(2)O(2) tetra­hedral coordination geometry. The dihedral angles between the aromatic rings in the ligands are 82.60 (14) and 71.79 (14)°. The complex has approximate local noncrystallographic twofold symmetry. In the crystal, weak aromatic π–π stacking is observed [centroid–centroid separation = 3.6434 (18) Å]. International Union of Crystallography 2013-02-20 /pmc/articles/PMC3588491/ /pubmed/23476501 http://dx.doi.org/10.1107/S1600536813003747 Text en © Zhu and Jiao 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Gang
Jiao, Bao-Juan
Bis{2-bromo-4-chloro-6-[(E)-(2,6-di­methyl­phen­yl)imino­meth­yl]phenolato-κ(2) N,O}cobalt(II)
title Bis{2-bromo-4-chloro-6-[(E)-(2,6-di­methyl­phen­yl)imino­meth­yl]phenolato-κ(2) N,O}cobalt(II)
title_full Bis{2-bromo-4-chloro-6-[(E)-(2,6-di­methyl­phen­yl)imino­meth­yl]phenolato-κ(2) N,O}cobalt(II)
title_fullStr Bis{2-bromo-4-chloro-6-[(E)-(2,6-di­methyl­phen­yl)imino­meth­yl]phenolato-κ(2) N,O}cobalt(II)
title_full_unstemmed Bis{2-bromo-4-chloro-6-[(E)-(2,6-di­methyl­phen­yl)imino­meth­yl]phenolato-κ(2) N,O}cobalt(II)
title_short Bis{2-bromo-4-chloro-6-[(E)-(2,6-di­methyl­phen­yl)imino­meth­yl]phenolato-κ(2) N,O}cobalt(II)
title_sort bis{2-bromo-4-chloro-6-[(e)-(2,6-di­methyl­phen­yl)imino­meth­yl]phenolato-κ(2) n,o}cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588491/
https://www.ncbi.nlm.nih.gov/pubmed/23476501
http://dx.doi.org/10.1107/S1600536813003747
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AT jiaobaojuan bis2bromo4chloro6e26dimethylphenyliminomethylphenolatok2nocobaltii

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