2-Amino-6-methyl­pyridinium 3-chloro­benzoate

In the title salt, C(6)H(9)N(2) (+)·C(7)H(4)ClO(2) (−), the 3-chloro­benzoate anion shows a whole-mol­ecule disorder over two positions with a refined occupancy ratio of 0.505 (4):0.495 (4). In the crystal, the cations and anions are linked via N—H⋯O hydrogen bonds, forming a centrosymmetric 2 + 2 a...

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Autores principales: Thanigaimani, Kaliyaperumal, Khalib, Nuridayanti Che, Arshad, Suhana, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588495/
https://www.ncbi.nlm.nih.gov/pubmed/23476517
http://dx.doi.org/10.1107/S1600536813002559
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author Thanigaimani, Kaliyaperumal
Khalib, Nuridayanti Che
Arshad, Suhana
Razak, Ibrahim Abdul
author_facet Thanigaimani, Kaliyaperumal
Khalib, Nuridayanti Che
Arshad, Suhana
Razak, Ibrahim Abdul
author_sort Thanigaimani, Kaliyaperumal
collection PubMed
description In the title salt, C(6)H(9)N(2) (+)·C(7)H(4)ClO(2) (−), the 3-chloro­benzoate anion shows a whole-mol­ecule disorder over two positions with a refined occupancy ratio of 0.505 (4):0.495 (4). In the crystal, the cations and anions are linked via N—H⋯O hydrogen bonds, forming a centrosymmetric 2 + 2 aggregate with R (2) (2)(8) and R (4) (2)(8) ring motifs. The crystal structure also features a π–π stacking inter­action between the pyridinium rings with a centroid–centroid distance of 3.8339 (9) Å.
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spelling pubmed-35884952013-03-08 2-Amino-6-methyl­pyridinium 3-chloro­benzoate Thanigaimani, Kaliyaperumal Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(6)H(9)N(2) (+)·C(7)H(4)ClO(2) (−), the 3-chloro­benzoate anion shows a whole-mol­ecule disorder over two positions with a refined occupancy ratio of 0.505 (4):0.495 (4). In the crystal, the cations and anions are linked via N—H⋯O hydrogen bonds, forming a centrosymmetric 2 + 2 aggregate with R (2) (2)(8) and R (4) (2)(8) ring motifs. The crystal structure also features a π–π stacking inter­action between the pyridinium rings with a centroid–centroid distance of 3.8339 (9) Å. International Union of Crystallography 2013-02-02 /pmc/articles/PMC3588495/ /pubmed/23476517 http://dx.doi.org/10.1107/S1600536813002559 Text en © Thanigaimani et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thanigaimani, Kaliyaperumal
Khalib, Nuridayanti Che
Arshad, Suhana
Razak, Ibrahim Abdul
2-Amino-6-methyl­pyridinium 3-chloro­benzoate
title 2-Amino-6-methyl­pyridinium 3-chloro­benzoate
title_full 2-Amino-6-methyl­pyridinium 3-chloro­benzoate
title_fullStr 2-Amino-6-methyl­pyridinium 3-chloro­benzoate
title_full_unstemmed 2-Amino-6-methyl­pyridinium 3-chloro­benzoate
title_short 2-Amino-6-methyl­pyridinium 3-chloro­benzoate
title_sort 2-amino-6-methyl­pyridinium 3-chloro­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588495/
https://www.ncbi.nlm.nih.gov/pubmed/23476517
http://dx.doi.org/10.1107/S1600536813002559
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AT razakibrahimabdul 2amino6methylpyridinium3chlorobenzoate

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