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(1RS,2RS)-4,4′-(1-Azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium tetrachloridoplatinate(II) chloride
The title compound, (C(12)H(16)N(3)O)[PtCl(4)]Cl, consists of a 4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium trication, a square-planar tetrachloridoplatinate(II) dianion and a chloride ion. In the cation, the pyridinium rings attached to the central 1-azaniumyl-2-hydroxyethane fr...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588516/ https://www.ncbi.nlm.nih.gov/pubmed/23476502 http://dx.doi.org/10.1107/S160053681300425X |
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author | Campos-Gaxiola, José J. Almaral-Sanchez, Jorge L. Cruz-Enríquez, Adriana Höpfl, Herbert Parra-Hake, Miguel |
author_facet | Campos-Gaxiola, José J. Almaral-Sanchez, Jorge L. Cruz-Enríquez, Adriana Höpfl, Herbert Parra-Hake, Miguel |
author_sort | Campos-Gaxiola, José J. |
collection | PubMed |
description | The title compound, (C(12)H(16)N(3)O)[PtCl(4)]Cl, consists of a 4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium trication, a square-planar tetrachloridoplatinate(II) dianion and a chloride ion. In the cation, the pyridinium rings attached to the central 1-azaniumyl-2-hydroxyethane fragment have an anti conformation, as indicated by the central C—C—C—C torsion angle of −166.5 (6)°, and they are inclined to one another by 63.5 (4)°. In the crystal, the cations and anions are linked through N—H⋯Cl and O—H⋯Cl hydrogen bonds. There are also π–π contacts [centroid–centroid distances = 3.671 (4) and 3.851 (4) Å] and a number of C—H⋯Cl interactions present, consolidating the formation of a three-dimensional supramolecular structure. |
format | Online Article Text |
id | pubmed-3588516 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35885162013-03-08 (1RS,2RS)-4,4′-(1-Azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium tetrachloridoplatinate(II) chloride Campos-Gaxiola, José J. Almaral-Sanchez, Jorge L. Cruz-Enríquez, Adriana Höpfl, Herbert Parra-Hake, Miguel Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(12)H(16)N(3)O)[PtCl(4)]Cl, consists of a 4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium trication, a square-planar tetrachloridoplatinate(II) dianion and a chloride ion. In the cation, the pyridinium rings attached to the central 1-azaniumyl-2-hydroxyethane fragment have an anti conformation, as indicated by the central C—C—C—C torsion angle of −166.5 (6)°, and they are inclined to one another by 63.5 (4)°. In the crystal, the cations and anions are linked through N—H⋯Cl and O—H⋯Cl hydrogen bonds. There are also π–π contacts [centroid–centroid distances = 3.671 (4) and 3.851 (4) Å] and a number of C—H⋯Cl interactions present, consolidating the formation of a three-dimensional supramolecular structure. International Union of Crystallography 2013-02-20 /pmc/articles/PMC3588516/ /pubmed/23476502 http://dx.doi.org/10.1107/S160053681300425X Text en © Campos-Gaxiola et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Campos-Gaxiola, José J. Almaral-Sanchez, Jorge L. Cruz-Enríquez, Adriana Höpfl, Herbert Parra-Hake, Miguel (1RS,2RS)-4,4′-(1-Azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium tetrachloridoplatinate(II) chloride |
title | (1RS,2RS)-4,4′-(1-Azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium tetrachloridoplatinate(II) chloride |
title_full | (1RS,2RS)-4,4′-(1-Azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium tetrachloridoplatinate(II) chloride |
title_fullStr | (1RS,2RS)-4,4′-(1-Azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium tetrachloridoplatinate(II) chloride |
title_full_unstemmed | (1RS,2RS)-4,4′-(1-Azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium tetrachloridoplatinate(II) chloride |
title_short | (1RS,2RS)-4,4′-(1-Azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium tetrachloridoplatinate(II) chloride |
title_sort | (1rs,2rs)-4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium tetrachloridoplatinate(ii) chloride |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588516/ https://www.ncbi.nlm.nih.gov/pubmed/23476502 http://dx.doi.org/10.1107/S160053681300425X |
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