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(1RS,2RS)-4,4′-(1-Aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium tetra­chlorido­platinate(II) chloride

The title compound, (C(12)H(16)N(3)O)[PtCl(4)]Cl, consists of a 4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium trication, a square-planar tetra­chloridoplatinate(II) dianion and a chloride ion. In the cation, the pyridinium rings attached to the central 1-aza­niumyl-2-hy­droxy­ethane fr...

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Autores principales: Campos-Gaxiola, José J., Almaral-Sanchez, Jorge L., Cruz-Enríquez, Adriana, Höpfl, Herbert, Parra-Hake, Miguel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588516/
https://www.ncbi.nlm.nih.gov/pubmed/23476502
http://dx.doi.org/10.1107/S160053681300425X
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author Campos-Gaxiola, José J.
Almaral-Sanchez, Jorge L.
Cruz-Enríquez, Adriana
Höpfl, Herbert
Parra-Hake, Miguel
author_facet Campos-Gaxiola, José J.
Almaral-Sanchez, Jorge L.
Cruz-Enríquez, Adriana
Höpfl, Herbert
Parra-Hake, Miguel
author_sort Campos-Gaxiola, José J.
collection PubMed
description The title compound, (C(12)H(16)N(3)O)[PtCl(4)]Cl, consists of a 4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium trication, a square-planar tetra­chloridoplatinate(II) dianion and a chloride ion. In the cation, the pyridinium rings attached to the central 1-aza­niumyl-2-hy­droxy­ethane fragment have an anti conformation, as indicated by the central C—C—C—C torsion angle of −166.5 (6)°, and they are inclined to one another by 63.5 (4)°. In the crystal, the cations and anions are linked through N—H⋯Cl and O—H⋯Cl hydrogen bonds. There are also π–π contacts [centroid–centroid distances = 3.671 (4) and 3.851 (4) Å] and a number of C—H⋯Cl inter­actions present, consolidating the formation of a three-dimensional supra­molecular structure.
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spelling pubmed-35885162013-03-08 (1RS,2RS)-4,4′-(1-Aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium tetra­chlorido­platinate(II) chloride Campos-Gaxiola, José J. Almaral-Sanchez, Jorge L. Cruz-Enríquez, Adriana Höpfl, Herbert Parra-Hake, Miguel Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(12)H(16)N(3)O)[PtCl(4)]Cl, consists of a 4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium trication, a square-planar tetra­chloridoplatinate(II) dianion and a chloride ion. In the cation, the pyridinium rings attached to the central 1-aza­niumyl-2-hy­droxy­ethane fragment have an anti conformation, as indicated by the central C—C—C—C torsion angle of −166.5 (6)°, and they are inclined to one another by 63.5 (4)°. In the crystal, the cations and anions are linked through N—H⋯Cl and O—H⋯Cl hydrogen bonds. There are also π–π contacts [centroid–centroid distances = 3.671 (4) and 3.851 (4) Å] and a number of C—H⋯Cl inter­actions present, consolidating the formation of a three-dimensional supra­molecular structure. International Union of Crystallography 2013-02-20 /pmc/articles/PMC3588516/ /pubmed/23476502 http://dx.doi.org/10.1107/S160053681300425X Text en © Campos-Gaxiola et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Campos-Gaxiola, José J.
Almaral-Sanchez, Jorge L.
Cruz-Enríquez, Adriana
Höpfl, Herbert
Parra-Hake, Miguel
(1RS,2RS)-4,4′-(1-Aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium tetra­chlorido­platinate(II) chloride
title (1RS,2RS)-4,4′-(1-Aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium tetra­chlorido­platinate(II) chloride
title_full (1RS,2RS)-4,4′-(1-Aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium tetra­chlorido­platinate(II) chloride
title_fullStr (1RS,2RS)-4,4′-(1-Aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium tetra­chlorido­platinate(II) chloride
title_full_unstemmed (1RS,2RS)-4,4′-(1-Aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium tetra­chlorido­platinate(II) chloride
title_short (1RS,2RS)-4,4′-(1-Aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium tetra­chlorido­platinate(II) chloride
title_sort (1rs,2rs)-4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium tetra­chlorido­platinate(ii) chloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588516/
https://www.ncbi.nlm.nih.gov/pubmed/23476502
http://dx.doi.org/10.1107/S160053681300425X
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