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Diethyl 1,8-diphenyl-11-oxatricyclo­[6.2.1.0(2,7)]undeca-2,4,6-triene-9,10-dicarboxyl­ate

The title compound, C(28)H(26)O(5), is the Diels–Alder adduct from 1,3-diphenyl­benzo[c]furan and diethyl maleate. The mol­ecule comprises of a fused tricyclic system containing two five-membered rings, which are in envelope conformations with the O atom at the flap, and a six-membered ring adopting...

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Detalles Bibliográficos
Autores principales: Balakrishnan, B., Nandakumar, Meganathan, Seshadri, P. R., Mohanakrishnan, Arasambattu K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588525/
https://www.ncbi.nlm.nih.gov/pubmed/23476521
http://dx.doi.org/10.1107/S1600536813002791
Descripción
Sumario:The title compound, C(28)H(26)O(5), is the Diels–Alder adduct from 1,3-diphenyl­benzo[c]furan and diethyl maleate. The mol­ecule comprises of a fused tricyclic system containing two five-membered rings, which are in envelope conformations with the O atom at the flap, and a six-membered ring adopting a boat conformation. The dihedral angle between phenyl substituents in the 1,8-positions is 55.1 (1)°. The ethyl groups are disordered over two sets of sites, with occupancy ratios of 0.648 (9):0.352 (9) and 0.816 (1):0.184 (1). In the crystal, pairs of C—H⋯π inter­actions link the mol­ecules into inversion dimers.