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Diethyl 1,8-diphenyl-11-oxatricyclo­[6.2.1.0(2,7)]undeca-2,4,6-triene-9,10-dicarboxyl­ate

The title compound, C(28)H(26)O(5), is the Diels–Alder adduct from 1,3-diphenyl­benzo[c]furan and diethyl maleate. The mol­ecule comprises of a fused tricyclic system containing two five-membered rings, which are in envelope conformations with the O atom at the flap, and a six-membered ring adopting...

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Autores principales: Balakrishnan, B., Nandakumar, Meganathan, Seshadri, P. R., Mohanakrishnan, Arasambattu K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588525/
https://www.ncbi.nlm.nih.gov/pubmed/23476521
http://dx.doi.org/10.1107/S1600536813002791
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author Balakrishnan, B.
Nandakumar, Meganathan
Seshadri, P. R.
Mohanakrishnan, Arasambattu K.
author_facet Balakrishnan, B.
Nandakumar, Meganathan
Seshadri, P. R.
Mohanakrishnan, Arasambattu K.
author_sort Balakrishnan, B.
collection PubMed
description The title compound, C(28)H(26)O(5), is the Diels–Alder adduct from 1,3-diphenyl­benzo[c]furan and diethyl maleate. The mol­ecule comprises of a fused tricyclic system containing two five-membered rings, which are in envelope conformations with the O atom at the flap, and a six-membered ring adopting a boat conformation. The dihedral angle between phenyl substituents in the 1,8-positions is 55.1 (1)°. The ethyl groups are disordered over two sets of sites, with occupancy ratios of 0.648 (9):0.352 (9) and 0.816 (1):0.184 (1). In the crystal, pairs of C—H⋯π inter­actions link the mol­ecules into inversion dimers.
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spelling pubmed-35885252013-03-08 Diethyl 1,8-diphenyl-11-oxatricyclo­[6.2.1.0(2,7)]undeca-2,4,6-triene-9,10-dicarboxyl­ate Balakrishnan, B. Nandakumar, Meganathan Seshadri, P. R. Mohanakrishnan, Arasambattu K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(28)H(26)O(5), is the Diels–Alder adduct from 1,3-diphenyl­benzo[c]furan and diethyl maleate. The mol­ecule comprises of a fused tricyclic system containing two five-membered rings, which are in envelope conformations with the O atom at the flap, and a six-membered ring adopting a boat conformation. The dihedral angle between phenyl substituents in the 1,8-positions is 55.1 (1)°. The ethyl groups are disordered over two sets of sites, with occupancy ratios of 0.648 (9):0.352 (9) and 0.816 (1):0.184 (1). In the crystal, pairs of C—H⋯π inter­actions link the mol­ecules into inversion dimers. International Union of Crystallography 2013-02-02 /pmc/articles/PMC3588525/ /pubmed/23476521 http://dx.doi.org/10.1107/S1600536813002791 Text en © Balakrishnan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Balakrishnan, B.
Nandakumar, Meganathan
Seshadri, P. R.
Mohanakrishnan, Arasambattu K.
Diethyl 1,8-diphenyl-11-oxatricyclo­[6.2.1.0(2,7)]undeca-2,4,6-triene-9,10-dicarboxyl­ate
title Diethyl 1,8-diphenyl-11-oxatricyclo­[6.2.1.0(2,7)]undeca-2,4,6-triene-9,10-dicarboxyl­ate
title_full Diethyl 1,8-diphenyl-11-oxatricyclo­[6.2.1.0(2,7)]undeca-2,4,6-triene-9,10-dicarboxyl­ate
title_fullStr Diethyl 1,8-diphenyl-11-oxatricyclo­[6.2.1.0(2,7)]undeca-2,4,6-triene-9,10-dicarboxyl­ate
title_full_unstemmed Diethyl 1,8-diphenyl-11-oxatricyclo­[6.2.1.0(2,7)]undeca-2,4,6-triene-9,10-dicarboxyl­ate
title_short Diethyl 1,8-diphenyl-11-oxatricyclo­[6.2.1.0(2,7)]undeca-2,4,6-triene-9,10-dicarboxyl­ate
title_sort diethyl 1,8-diphenyl-11-oxatricyclo­[6.2.1.0(2,7)]undeca-2,4,6-triene-9,10-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588525/
https://www.ncbi.nlm.nih.gov/pubmed/23476521
http://dx.doi.org/10.1107/S1600536813002791
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