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3-Chloro-4-[2-(4-chlorobenzylidene)hydrazinylidene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothiazine-2,2-dione
In the title compound, C(16)H(13)Cl(2)N(3)O(2)S, the dihedral angle between the aromatic rings is 6.62 (2)° and the C=N—N=C torsion angle is 176.2 (4)°. The thiazine ring shows an envelope conformation, with the S atom displaced by 0.633 (6) Å from the mean plane of the other five atoms (r.m.s. dev...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588526/ https://www.ncbi.nlm.nih.gov/pubmed/23476596 http://dx.doi.org/10.1107/S1600536813004443 |
Sumario: | In the title compound, C(16)H(13)Cl(2)N(3)O(2)S, the dihedral angle between the aromatic rings is 6.62 (2)° and the C=N—N=C torsion angle is 176.2 (4)°. The thiazine ring shows an envelope conformation, with the S atom displaced by 0.633 (6) Å from the mean plane of the other five atoms (r.m.s. deviation = 0.037 Å). The Cl atom is an an axial conformation and is displaced by 2.015 (6) Å from the thiazine ring plane. In the crystal, molecules are linked by C—H⋯O interactions, generating a three-dimensional network. Very weak aromatic π–π stacking interactions [centroid–centroid separations = 3.928 (2) Å] are also observed. |
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