The non-centrosymmetric polymorph of (quinolin-8-ol-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)silver(I)

The title compound, [Ag(C(9)H(6)NO)(C(9)H(7)NO)], crystallizes as a non-centrosymmetric polymorph. The structure was previously reported by Wu et al. [(2006). Acta Cryst. E62, m281–m282] in the centrosymmetric space group Pbcn. The Ag(I) ion displays a distorted tetra­hedral coordination geometry de...

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Detalles Bibliográficos
Autores principales: Jia, Zhen-Bin, Zhao, Yi, Wen, Qiu-Jia, Ma, Ai-Qing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588529/
https://www.ncbi.nlm.nih.gov/pubmed/23476483
http://dx.doi.org/10.1107/S160053681300281X
Descripción
Sumario:The title compound, [Ag(C(9)H(6)NO)(C(9)H(7)NO)], crystallizes as a non-centrosymmetric polymorph. The structure was previously reported by Wu et al. [(2006). Acta Cryst. E62, m281–m282] in the centrosymmetric space group Pbcn. The Ag(I) ion displays a distorted tetra­hedral coordination geometry defined by two N and two O atoms from a neutral quinolin-8-ol ligand (HQ) and a deprotonated quinolin-8-olate anion (Q(−)). The dihedral angle between the two ligands is 47.0 (1)°. Strong O—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular chain along the a-axis direction.

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