The non-centrosymmetric polymorph of (quinolin-8-ol-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)silver(I)

The title compound, [Ag(C(9)H(6)NO)(C(9)H(7)NO)], crystallizes as a non-centrosymmetric polymorph. The structure was previously reported by Wu et al. [(2006). Acta Cryst. E62, m281–m282] in the centrosymmetric space group Pbcn. The Ag(I) ion displays a distorted tetra­hedral coordination geometry de...

Descripción completa

Detalles Bibliográficos
Autores principales: Jia, Zhen-Bin, Zhao, Yi, Wen, Qiu-Jia, Ma, Ai-Qing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588529/
https://www.ncbi.nlm.nih.gov/pubmed/23476483
http://dx.doi.org/10.1107/S160053681300281X
_version_ 1782261586591744000
author Jia, Zhen-Bin
Zhao, Yi
Wen, Qiu-Jia
Ma, Ai-Qing
author_facet Jia, Zhen-Bin
Zhao, Yi
Wen, Qiu-Jia
Ma, Ai-Qing
author_sort Jia, Zhen-Bin
collection PubMed
description The title compound, [Ag(C(9)H(6)NO)(C(9)H(7)NO)], crystallizes as a non-centrosymmetric polymorph. The structure was previously reported by Wu et al. [(2006). Acta Cryst. E62, m281–m282] in the centrosymmetric space group Pbcn. The Ag(I) ion displays a distorted tetra­hedral coordination geometry defined by two N and two O atoms from a neutral quinolin-8-ol ligand (HQ) and a deprotonated quinolin-8-olate anion (Q(−)). The dihedral angle between the two ligands is 47.0 (1)°. Strong O—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular chain along the a-axis direction.
format Online
Article
Text
id pubmed-3588529
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35885292013-03-08 The non-centrosymmetric polymorph of (quinolin-8-ol-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)silver(I) Jia, Zhen-Bin Zhao, Yi Wen, Qiu-Jia Ma, Ai-Qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ag(C(9)H(6)NO)(C(9)H(7)NO)], crystallizes as a non-centrosymmetric polymorph. The structure was previously reported by Wu et al. [(2006). Acta Cryst. E62, m281–m282] in the centrosymmetric space group Pbcn. The Ag(I) ion displays a distorted tetra­hedral coordination geometry defined by two N and two O atoms from a neutral quinolin-8-ol ligand (HQ) and a deprotonated quinolin-8-olate anion (Q(−)). The dihedral angle between the two ligands is 47.0 (1)°. Strong O—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular chain along the a-axis direction. International Union of Crystallography 2013-02-02 /pmc/articles/PMC3588529/ /pubmed/23476483 http://dx.doi.org/10.1107/S160053681300281X Text en © Jia et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jia, Zhen-Bin
Zhao, Yi
Wen, Qiu-Jia
Ma, Ai-Qing
The non-centrosymmetric polymorph of (quinolin-8-ol-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)silver(I)
title The non-centrosymmetric polymorph of (quinolin-8-ol-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)silver(I)
title_full The non-centrosymmetric polymorph of (quinolin-8-ol-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)silver(I)
title_fullStr The non-centrosymmetric polymorph of (quinolin-8-ol-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)silver(I)
title_full_unstemmed The non-centrosymmetric polymorph of (quinolin-8-ol-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)silver(I)
title_short The non-centrosymmetric polymorph of (quinolin-8-ol-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)silver(I)
title_sort non-centrosymmetric polymorph of (quinolin-8-ol-κ(2) n,o)(quinolin-8-olato-κ(2) n,o)silver(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588529/
https://www.ncbi.nlm.nih.gov/pubmed/23476483
http://dx.doi.org/10.1107/S160053681300281X
work_keys_str_mv AT jiazhenbin thenoncentrosymmetricpolymorphofquinolin8olk2noquinolin8olatok2nosilveri
AT zhaoyi thenoncentrosymmetricpolymorphofquinolin8olk2noquinolin8olatok2nosilveri
AT wenqiujia thenoncentrosymmetricpolymorphofquinolin8olk2noquinolin8olatok2nosilveri
AT maaiqing thenoncentrosymmetricpolymorphofquinolin8olk2noquinolin8olatok2nosilveri
AT jiazhenbin noncentrosymmetricpolymorphofquinolin8olk2noquinolin8olatok2nosilveri
AT zhaoyi noncentrosymmetricpolymorphofquinolin8olk2noquinolin8olatok2nosilveri
AT wenqiujia noncentrosymmetricpolymorphofquinolin8olk2noquinolin8olatok2nosilveri
AT maaiqing noncentrosymmetricpolymorphofquinolin8olk2noquinolin8olatok2nosilveri

Ejemplares similares