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4-(4-Meth­oxy­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbonitrile

In the title compound, C(20)H(17)N(3)O(4), the central pyran ring adopts a boat conformation with the O atom and diagonally opposite C atoms displaced by 0.1171 (1) and 0.1791 (1) Å, respectively, from the mean plane defined by the other four atoms. The coplanar atoms of the pyran ring and the meth­...

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Detalles Bibliográficos
Autores principales: Vishnupriya, R., Suresh, J., Sivakumar, S., Kumar, R. Ranjith, Lakshman, P. L. Nilantha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588539/
https://www.ncbi.nlm.nih.gov/pubmed/23476619
http://dx.doi.org/10.1107/S1600536813004923
Descripción
Sumario:In the title compound, C(20)H(17)N(3)O(4), the central pyran ring adopts a boat conformation with the O atom and diagonally opposite C atoms displaced by 0.1171 (1) and 0.1791 (1) Å, respectively, from the mean plane defined by the other four atoms. The coplanar atoms of the pyran ring and the meth­oxy­benzene ring are nearly perpendicular, as evidenced by the dihedral angle 87.01 (1)°. The amine H atom forms an intra­molecular N—H⋯O(nitro) hydrogen bond. In the crystal, mol­ecules are linked into dimeric aggregates by N—H⋯O(nitro) hydrogen bonds, generating an R (2) (2)(12) graph-set motif.