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4-(4-Meth­oxy­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbonitrile

In the title compound, C(20)H(17)N(3)O(4), the central pyran ring adopts a boat conformation with the O atom and diagonally opposite C atoms displaced by 0.1171 (1) and 0.1791 (1) Å, respectively, from the mean plane defined by the other four atoms. The coplanar atoms of the pyran ring and the meth­...

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Autores principales: Vishnupriya, R., Suresh, J., Sivakumar, S., Kumar, R. Ranjith, Lakshman, P. L. Nilantha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588539/
https://www.ncbi.nlm.nih.gov/pubmed/23476619
http://dx.doi.org/10.1107/S1600536813004923
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author Vishnupriya, R.
Suresh, J.
Sivakumar, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
author_facet Vishnupriya, R.
Suresh, J.
Sivakumar, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
author_sort Vishnupriya, R.
collection PubMed
description In the title compound, C(20)H(17)N(3)O(4), the central pyran ring adopts a boat conformation with the O atom and diagonally opposite C atoms displaced by 0.1171 (1) and 0.1791 (1) Å, respectively, from the mean plane defined by the other four atoms. The coplanar atoms of the pyran ring and the meth­oxy­benzene ring are nearly perpendicular, as evidenced by the dihedral angle 87.01 (1)°. The amine H atom forms an intra­molecular N—H⋯O(nitro) hydrogen bond. In the crystal, mol­ecules are linked into dimeric aggregates by N—H⋯O(nitro) hydrogen bonds, generating an R (2) (2)(12) graph-set motif.
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spelling pubmed-35885392013-03-08 4-(4-Meth­oxy­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbonitrile Vishnupriya, R. Suresh, J. Sivakumar, S. Kumar, R. Ranjith Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(17)N(3)O(4), the central pyran ring adopts a boat conformation with the O atom and diagonally opposite C atoms displaced by 0.1171 (1) and 0.1791 (1) Å, respectively, from the mean plane defined by the other four atoms. The coplanar atoms of the pyran ring and the meth­oxy­benzene ring are nearly perpendicular, as evidenced by the dihedral angle 87.01 (1)°. The amine H atom forms an intra­molecular N—H⋯O(nitro) hydrogen bond. In the crystal, mol­ecules are linked into dimeric aggregates by N—H⋯O(nitro) hydrogen bonds, generating an R (2) (2)(12) graph-set motif. International Union of Crystallography 2013-02-28 /pmc/articles/PMC3588539/ /pubmed/23476619 http://dx.doi.org/10.1107/S1600536813004923 Text en © Vishnupriya et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vishnupriya, R.
Suresh, J.
Sivakumar, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
4-(4-Meth­oxy­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbonitrile
title 4-(4-Meth­oxy­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbonitrile
title_full 4-(4-Meth­oxy­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbonitrile
title_fullStr 4-(4-Meth­oxy­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbonitrile
title_full_unstemmed 4-(4-Meth­oxy­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbonitrile
title_short 4-(4-Meth­oxy­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4H-pyran-3-carbonitrile
title_sort 4-(4-meth­oxy­phen­yl)-6-methyl­amino-5-nitro-2-phenyl-4h-pyran-3-carbonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588539/
https://www.ncbi.nlm.nih.gov/pubmed/23476619
http://dx.doi.org/10.1107/S1600536813004923
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