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(8-Benzoyl-2,7-dimeth­oxy­naphthalen-1-yl)(4-phen­oxy­phen­yl)methanone

In the mol­ecule of the title compound, C(32)H(24)O(5), the benzoyl group and the 4-phenoxy substituted benzoyl group at the 1- and 8-positions of the naphthalene ring system are aligned almost anti­parallel. The two benzene rings make a dihedral angle of 21.18 (10)°, and are inclined to the naphtha...

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Autores principales: Sasagawa, Kosuke, Sakamoto, Rei, Takeuchi, Ryo, Yonezawa, Noriyuki, Okamoto, Akiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588546/
https://www.ncbi.nlm.nih.gov/pubmed/23476579
http://dx.doi.org/10.1107/S1600536813004303
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author Sasagawa, Kosuke
Sakamoto, Rei
Takeuchi, Ryo
Yonezawa, Noriyuki
Okamoto, Akiko
author_facet Sasagawa, Kosuke
Sakamoto, Rei
Takeuchi, Ryo
Yonezawa, Noriyuki
Okamoto, Akiko
author_sort Sasagawa, Kosuke
collection PubMed
description In the mol­ecule of the title compound, C(32)H(24)O(5), the benzoyl group and the 4-phenoxy substituted benzoyl group at the 1- and 8-positions of the naphthalene ring system are aligned almost anti­parallel. The two benzene rings make a dihedral angle of 21.18 (10)°, and are inclined to the naphthalene ring system by 86.53 (9) and 82.95 (8)°, respectively. In the crystal, C—H⋯O inter­actions are observed involving aromatic and meth­oxy H atoms with ketonic carbonyl O atoms, as well as C—H⋯π inter­actions between aromatic H atoms and the π-systems of naphthalene and benzene rings. These interactions form a three-dimensional architecture and afford a waved alignment of the naphthalene ring systems along the c axis.
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spelling pubmed-35885462013-03-08 (8-Benzoyl-2,7-dimeth­oxy­naphthalen-1-yl)(4-phen­oxy­phen­yl)methanone Sasagawa, Kosuke Sakamoto, Rei Takeuchi, Ryo Yonezawa, Noriyuki Okamoto, Akiko Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(32)H(24)O(5), the benzoyl group and the 4-phenoxy substituted benzoyl group at the 1- and 8-positions of the naphthalene ring system are aligned almost anti­parallel. The two benzene rings make a dihedral angle of 21.18 (10)°, and are inclined to the naphthalene ring system by 86.53 (9) and 82.95 (8)°, respectively. In the crystal, C—H⋯O inter­actions are observed involving aromatic and meth­oxy H atoms with ketonic carbonyl O atoms, as well as C—H⋯π inter­actions between aromatic H atoms and the π-systems of naphthalene and benzene rings. These interactions form a three-dimensional architecture and afford a waved alignment of the naphthalene ring systems along the c axis. International Union of Crystallography 2013-02-20 /pmc/articles/PMC3588546/ /pubmed/23476579 http://dx.doi.org/10.1107/S1600536813004303 Text en © Sasagawa et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sasagawa, Kosuke
Sakamoto, Rei
Takeuchi, Ryo
Yonezawa, Noriyuki
Okamoto, Akiko
(8-Benzoyl-2,7-dimeth­oxy­naphthalen-1-yl)(4-phen­oxy­phen­yl)methanone
title (8-Benzoyl-2,7-dimeth­oxy­naphthalen-1-yl)(4-phen­oxy­phen­yl)methanone
title_full (8-Benzoyl-2,7-dimeth­oxy­naphthalen-1-yl)(4-phen­oxy­phen­yl)methanone
title_fullStr (8-Benzoyl-2,7-dimeth­oxy­naphthalen-1-yl)(4-phen­oxy­phen­yl)methanone
title_full_unstemmed (8-Benzoyl-2,7-dimeth­oxy­naphthalen-1-yl)(4-phen­oxy­phen­yl)methanone
title_short (8-Benzoyl-2,7-dimeth­oxy­naphthalen-1-yl)(4-phen­oxy­phen­yl)methanone
title_sort (8-benzoyl-2,7-dimeth­oxy­naphthalen-1-yl)(4-phen­oxy­phen­yl)methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588546/
https://www.ncbi.nlm.nih.gov/pubmed/23476579
http://dx.doi.org/10.1107/S1600536813004303
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