(E)-2-[4-(Diethyl­amino)­styr­yl]-1-ethyl­pyridinium iodide monohydrate

In the title hydrated salt, C(19)H(25)N(2) (+)·I(−)·H(2)O, the 4-(diethyl­amino)­phenyl unit of the cation is disordered over two positions in a 0.847 (3):0.153 (3) ratio. The cation is twisted, with dihedral angles between the pyridinium and benzene rings of 11.25 (13) and 10.7 (8)° for the major a...

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Autores principales: Chantrapromma, Suchada, Boonnak, Nawong, Kaewmanee, Narissara, Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588554/
https://www.ncbi.nlm.nih.gov/pubmed/23476625
http://dx.doi.org/10.1107/S160053681300528X
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author Chantrapromma, Suchada
Boonnak, Nawong
Kaewmanee, Narissara
Quah, Ching Kheng
Fun, Hoong-Kun
author_facet Chantrapromma, Suchada
Boonnak, Nawong
Kaewmanee, Narissara
Quah, Ching Kheng
Fun, Hoong-Kun
author_sort Chantrapromma, Suchada
collection PubMed
description In the title hydrated salt, C(19)H(25)N(2) (+)·I(−)·H(2)O, the 4-(diethyl­amino)­phenyl unit of the cation is disordered over two positions in a 0.847 (3):0.153 (3) ratio. The cation is twisted, with dihedral angles between the pyridinium and benzene rings of 11.25 (13) and 10.7 (8)° for the major and minor components, respectively. In the crystal, the three components are linked into a centrosymmetric 2:2:2 unit by O—H⋯I and C—H⋯O hydrogen bonds. π–π inter­actions with centroid–centroid distances of 3.5065 (7)–3.790 (9) Å are also present.
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spelling pubmed-35885542013-03-08 (E)-2-[4-(Diethyl­amino)­styr­yl]-1-ethyl­pyridinium iodide monohydrate Chantrapromma, Suchada Boonnak, Nawong Kaewmanee, Narissara Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated salt, C(19)H(25)N(2) (+)·I(−)·H(2)O, the 4-(diethyl­amino)­phenyl unit of the cation is disordered over two positions in a 0.847 (3):0.153 (3) ratio. The cation is twisted, with dihedral angles between the pyridinium and benzene rings of 11.25 (13) and 10.7 (8)° for the major and minor components, respectively. In the crystal, the three components are linked into a centrosymmetric 2:2:2 unit by O—H⋯I and C—H⋯O hydrogen bonds. π–π inter­actions with centroid–centroid distances of 3.5065 (7)–3.790 (9) Å are also present. International Union of Crystallography 2013-02-28 /pmc/articles/PMC3588554/ /pubmed/23476625 http://dx.doi.org/10.1107/S160053681300528X Text en © Chantrapromma et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chantrapromma, Suchada
Boonnak, Nawong
Kaewmanee, Narissara
Quah, Ching Kheng
Fun, Hoong-Kun
(E)-2-[4-(Diethyl­amino)­styr­yl]-1-ethyl­pyridinium iodide monohydrate
title (E)-2-[4-(Diethyl­amino)­styr­yl]-1-ethyl­pyridinium iodide monohydrate
title_full (E)-2-[4-(Diethyl­amino)­styr­yl]-1-ethyl­pyridinium iodide monohydrate
title_fullStr (E)-2-[4-(Diethyl­amino)­styr­yl]-1-ethyl­pyridinium iodide monohydrate
title_full_unstemmed (E)-2-[4-(Diethyl­amino)­styr­yl]-1-ethyl­pyridinium iodide monohydrate
title_short (E)-2-[4-(Diethyl­amino)­styr­yl]-1-ethyl­pyridinium iodide monohydrate
title_sort (e)-2-[4-(diethyl­amino)­styr­yl]-1-ethyl­pyridinium iodide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588554/
https://www.ncbi.nlm.nih.gov/pubmed/23476625
http://dx.doi.org/10.1107/S160053681300528X
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