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(Z)-N-[2-(N′-Hy­droxy­carbamimido­yl)phen­yl]acetamide

The asymmetric unit of the title compound, C(9)H(11)N(3)O(2), contains two mol­ecules (A and B), which exist in Z conformations with respect to their C=N double bond. The dihedral angles between the benzene ring and the pendant hy­droxy­carbamimidoyl and acetamide groups are 28.58 (7) and 1.30 (5)°,...

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Autores principales: Fun, Hoong-Kun, Ooi, Chin Wei, Dinesha, Viveka, S., Nagaraja, G.K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588555/
https://www.ncbi.nlm.nih.gov/pubmed/23476559
http://dx.doi.org/10.1107/S1600536813003371
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author Fun, Hoong-Kun
Ooi, Chin Wei
Dinesha,
Viveka, S.
Nagaraja, G.K.
author_facet Fun, Hoong-Kun
Ooi, Chin Wei
Dinesha,
Viveka, S.
Nagaraja, G.K.
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title compound, C(9)H(11)N(3)O(2), contains two mol­ecules (A and B), which exist in Z conformations with respect to their C=N double bond. The dihedral angles between the benzene ring and the pendant hy­droxy­carbamimidoyl and acetamide groups are 28.58 (7) and 1.30 (5)°, respectively, in mol­ecule A and 25.04 (7) and 27.85 (9)°, respectively, in mol­ecule B. An intra­molecular N—H⋯N hydrogen bond generates an S(6) ring in both mol­ecules. Mol­ecule A also features an intra­molecular C—H⋯O inter­action, which closes an S(6) ring. In the crystal, the mol­ecules are linked by N—H⋯O, N—H⋯N, O—H⋯O, O—H⋯N, C—H⋯O and C—H⋯N hydrogen bonds and C—H⋯π inter­actions, generating a three-dimensional network.
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spelling pubmed-35885552013-03-08 (Z)-N-[2-(N′-Hy­droxy­carbamimido­yl)phen­yl]acetamide Fun, Hoong-Kun Ooi, Chin Wei Dinesha, Viveka, S. Nagaraja, G.K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(9)H(11)N(3)O(2), contains two mol­ecules (A and B), which exist in Z conformations with respect to their C=N double bond. The dihedral angles between the benzene ring and the pendant hy­droxy­carbamimidoyl and acetamide groups are 28.58 (7) and 1.30 (5)°, respectively, in mol­ecule A and 25.04 (7) and 27.85 (9)°, respectively, in mol­ecule B. An intra­molecular N—H⋯N hydrogen bond generates an S(6) ring in both mol­ecules. Mol­ecule A also features an intra­molecular C—H⋯O inter­action, which closes an S(6) ring. In the crystal, the mol­ecules are linked by N—H⋯O, N—H⋯N, O—H⋯O, O—H⋯N, C—H⋯O and C—H⋯N hydrogen bonds and C—H⋯π inter­actions, generating a three-dimensional network. International Union of Crystallography 2013-02-09 /pmc/articles/PMC3588555/ /pubmed/23476559 http://dx.doi.org/10.1107/S1600536813003371 Text en © Fun et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Ooi, Chin Wei
Dinesha,
Viveka, S.
Nagaraja, G.K.
(Z)-N-[2-(N′-Hy­droxy­carbamimido­yl)phen­yl]acetamide
title (Z)-N-[2-(N′-Hy­droxy­carbamimido­yl)phen­yl]acetamide
title_full (Z)-N-[2-(N′-Hy­droxy­carbamimido­yl)phen­yl]acetamide
title_fullStr (Z)-N-[2-(N′-Hy­droxy­carbamimido­yl)phen­yl]acetamide
title_full_unstemmed (Z)-N-[2-(N′-Hy­droxy­carbamimido­yl)phen­yl]acetamide
title_short (Z)-N-[2-(N′-Hy­droxy­carbamimido­yl)phen­yl]acetamide
title_sort (z)-n-[2-(n′-hy­droxy­carbamimido­yl)phen­yl]acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588555/
https://www.ncbi.nlm.nih.gov/pubmed/23476559
http://dx.doi.org/10.1107/S1600536813003371
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