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(Z)-N-[2-(N′-Hydroxycarbamimidoyl)phenyl]acetamide
The asymmetric unit of the title compound, C(9)H(11)N(3)O(2), contains two molecules (A and B), which exist in Z conformations with respect to their C=N double bond. The dihedral angles between the benzene ring and the pendant hydroxycarbamimidoyl and acetamide groups are 28.58 (7) and 1.30 (5)°,...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588555/ https://www.ncbi.nlm.nih.gov/pubmed/23476559 http://dx.doi.org/10.1107/S1600536813003371 |
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author | Fun, Hoong-Kun Ooi, Chin Wei Dinesha, Viveka, S. Nagaraja, G.K. |
author_facet | Fun, Hoong-Kun Ooi, Chin Wei Dinesha, Viveka, S. Nagaraja, G.K. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | The asymmetric unit of the title compound, C(9)H(11)N(3)O(2), contains two molecules (A and B), which exist in Z conformations with respect to their C=N double bond. The dihedral angles between the benzene ring and the pendant hydroxycarbamimidoyl and acetamide groups are 28.58 (7) and 1.30 (5)°, respectively, in molecule A and 25.04 (7) and 27.85 (9)°, respectively, in molecule B. An intramolecular N—H⋯N hydrogen bond generates an S(6) ring in both molecules. Molecule A also features an intramolecular C—H⋯O interaction, which closes an S(6) ring. In the crystal, the molecules are linked by N—H⋯O, N—H⋯N, O—H⋯O, O—H⋯N, C—H⋯O and C—H⋯N hydrogen bonds and C—H⋯π interactions, generating a three-dimensional network. |
format | Online Article Text |
id | pubmed-3588555 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35885552013-03-08 (Z)-N-[2-(N′-Hydroxycarbamimidoyl)phenyl]acetamide Fun, Hoong-Kun Ooi, Chin Wei Dinesha, Viveka, S. Nagaraja, G.K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(9)H(11)N(3)O(2), contains two molecules (A and B), which exist in Z conformations with respect to their C=N double bond. The dihedral angles between the benzene ring and the pendant hydroxycarbamimidoyl and acetamide groups are 28.58 (7) and 1.30 (5)°, respectively, in molecule A and 25.04 (7) and 27.85 (9)°, respectively, in molecule B. An intramolecular N—H⋯N hydrogen bond generates an S(6) ring in both molecules. Molecule A also features an intramolecular C—H⋯O interaction, which closes an S(6) ring. In the crystal, the molecules are linked by N—H⋯O, N—H⋯N, O—H⋯O, O—H⋯N, C—H⋯O and C—H⋯N hydrogen bonds and C—H⋯π interactions, generating a three-dimensional network. International Union of Crystallography 2013-02-09 /pmc/articles/PMC3588555/ /pubmed/23476559 http://dx.doi.org/10.1107/S1600536813003371 Text en © Fun et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Ooi, Chin Wei Dinesha, Viveka, S. Nagaraja, G.K. (Z)-N-[2-(N′-Hydroxycarbamimidoyl)phenyl]acetamide |
title | (Z)-N-[2-(N′-Hydroxycarbamimidoyl)phenyl]acetamide |
title_full | (Z)-N-[2-(N′-Hydroxycarbamimidoyl)phenyl]acetamide |
title_fullStr | (Z)-N-[2-(N′-Hydroxycarbamimidoyl)phenyl]acetamide |
title_full_unstemmed | (Z)-N-[2-(N′-Hydroxycarbamimidoyl)phenyl]acetamide |
title_short | (Z)-N-[2-(N′-Hydroxycarbamimidoyl)phenyl]acetamide |
title_sort | (z)-n-[2-(n′-hydroxycarbamimidoyl)phenyl]acetamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588555/ https://www.ncbi.nlm.nih.gov/pubmed/23476559 http://dx.doi.org/10.1107/S1600536813003371 |
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