Li(0.17)Na(5.83)Mo(11)O(36)

The title mixed-alkali-metal molybdenium oxide, hexa­kis­(lithium/sodium) undeca­molybdate, was synthesized by solid-state reaction at 793 K. Its [Mo(11)O(36)](6−) framework is built up from MoO(6) octa­hedra and MoO(5) pyramids linked together by edges and vertices. The framework delimits two types...

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Detalles Bibliográficos
Autores principales: Ennajeh, Ines, Hamza, Hamadi, Zid, Mohamed Faouzi, Driss, Ahmed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588700/
https://www.ncbi.nlm.nih.gov/pubmed/23468665
http://dx.doi.org/10.1107/S1600536812044224
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author Ennajeh, Ines
Hamza, Hamadi
Zid, Mohamed Faouzi
Driss, Ahmed
author_facet Ennajeh, Ines
Hamza, Hamadi
Zid, Mohamed Faouzi
Driss, Ahmed
author_sort Ennajeh, Ines
collection PubMed
description The title mixed-alkali-metal molybdenium oxide, hexa­kis­(lithium/sodium) undeca­molybdate, was synthesized by solid-state reaction at 793 K. Its [Mo(11)O(36)](6−) framework is built up from MoO(6) octa­hedra and MoO(5) pyramids linked together by edges and vertices. The framework delimits two types of inter­secting tunnels running along [100] and [001], where the sodium and lithium ions are located. Two of the sodium ions and the lithium ion have fractional site occupancies. One of the Mo atoms has site symmetry 2, one sodium ion has site symmetry 2 and one has site symmetry -1, and the Li(+) ion has site symmetry 2. Structural relationships between the title compound and the anatase and Na(6)Mo(11)O(36) structures are discussed.
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spelling pubmed-35887002013-03-06 Li(0.17)Na(5.83)Mo(11)O(36) Ennajeh, Ines Hamza, Hamadi Zid, Mohamed Faouzi Driss, Ahmed Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title mixed-alkali-metal molybdenium oxide, hexa­kis­(lithium/sodium) undeca­molybdate, was synthesized by solid-state reaction at 793 K. Its [Mo(11)O(36)](6−) framework is built up from MoO(6) octa­hedra and MoO(5) pyramids linked together by edges and vertices. The framework delimits two types of inter­secting tunnels running along [100] and [001], where the sodium and lithium ions are located. Two of the sodium ions and the lithium ion have fractional site occupancies. One of the Mo atoms has site symmetry 2, one sodium ion has site symmetry 2 and one has site symmetry -1, and the Li(+) ion has site symmetry 2. Structural relationships between the title compound and the anatase and Na(6)Mo(11)O(36) structures are discussed. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588700/ /pubmed/23468665 http://dx.doi.org/10.1107/S1600536812044224 Text en © Ennajeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Ennajeh, Ines
Hamza, Hamadi
Zid, Mohamed Faouzi
Driss, Ahmed
Li(0.17)Na(5.83)Mo(11)O(36)
title Li(0.17)Na(5.83)Mo(11)O(36)
title_full Li(0.17)Na(5.83)Mo(11)O(36)
title_fullStr Li(0.17)Na(5.83)Mo(11)O(36)
title_full_unstemmed Li(0.17)Na(5.83)Mo(11)O(36)
title_short Li(0.17)Na(5.83)Mo(11)O(36)
title_sort li(0.17)na(5.83)mo(11)o(36)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588700/
https://www.ncbi.nlm.nih.gov/pubmed/23468665
http://dx.doi.org/10.1107/S1600536812044224
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