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The layered polyphosphide Ag(3.73(4))Zn(2.27(4))P(16)
The silver zinc hexadecaphosphide Ag(3.73(4))Zn(2.27(4))P(16) is the first polyphosphide in the ternary system Ag/Zn/P. It was synthesized from stoichiometric mixtures of Ag, Zn and P in the molar ratio 4:2:16, using AgI as a mineralizing agent in a gas-phase-assisted reaction. Ag(3.73(4))Zn(2.27(...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588702/ https://www.ncbi.nlm.nih.gov/pubmed/23468667 http://dx.doi.org/10.1107/S1600536812045667 |
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author | Köpf, Marianne Osters, Oliver Bawohl, Melanie Nilges, Tom |
author_facet | Köpf, Marianne Osters, Oliver Bawohl, Melanie Nilges, Tom |
author_sort | Köpf, Marianne |
collection | PubMed |
description | The silver zinc hexadecaphosphide Ag(3.73(4))Zn(2.27(4))P(16) is the first polyphosphide in the ternary system Ag/Zn/P. It was synthesized from stoichiometric mixtures of Ag, Zn and P in the molar ratio 4:2:16, using AgI as a mineralizing agent in a gas-phase-assisted reaction. Ag(3.73(4))Zn(2.27(4))P(16) crystallizes in the Cu(5)InP(16) structure type. The asymmetric unit contains two Ag/Zn sites with mixed occupancies and four P sites. One of the Ag/Zn sites is located on a twofold rotation axis. The polyanionic [P(16)]-substructure consists of corrugated six-membered rings that are connected into a layer via the 1-, 2-, 4- and 5-positions of the rings by a bridging P atom in each case. The layers extend parallel to the bc plane and are stacked along the a axis. Both Ag/Zn sites are tetrahedrally coordinated by P atoms. |
format | Online Article Text |
id | pubmed-3588702 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887022013-03-06 The layered polyphosphide Ag(3.73(4))Zn(2.27(4))P(16) Köpf, Marianne Osters, Oliver Bawohl, Melanie Nilges, Tom Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The silver zinc hexadecaphosphide Ag(3.73(4))Zn(2.27(4))P(16) is the first polyphosphide in the ternary system Ag/Zn/P. It was synthesized from stoichiometric mixtures of Ag, Zn and P in the molar ratio 4:2:16, using AgI as a mineralizing agent in a gas-phase-assisted reaction. Ag(3.73(4))Zn(2.27(4))P(16) crystallizes in the Cu(5)InP(16) structure type. The asymmetric unit contains two Ag/Zn sites with mixed occupancies and four P sites. One of the Ag/Zn sites is located on a twofold rotation axis. The polyanionic [P(16)]-substructure consists of corrugated six-membered rings that are connected into a layer via the 1-, 2-, 4- and 5-positions of the rings by a bridging P atom in each case. The layers extend parallel to the bc plane and are stacked along the a axis. Both Ag/Zn sites are tetrahedrally coordinated by P atoms. International Union of Crystallography 2012-11-10 /pmc/articles/PMC3588702/ /pubmed/23468667 http://dx.doi.org/10.1107/S1600536812045667 Text en © Köpf et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Inorganic Papers Köpf, Marianne Osters, Oliver Bawohl, Melanie Nilges, Tom The layered polyphosphide Ag(3.73(4))Zn(2.27(4))P(16) |
title | The layered polyphosphide Ag(3.73(4))Zn(2.27(4))P(16)
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title_full | The layered polyphosphide Ag(3.73(4))Zn(2.27(4))P(16)
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title_fullStr | The layered polyphosphide Ag(3.73(4))Zn(2.27(4))P(16)
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title_full_unstemmed | The layered polyphosphide Ag(3.73(4))Zn(2.27(4))P(16)
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title_short | The layered polyphosphide Ag(3.73(4))Zn(2.27(4))P(16)
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title_sort | layered polyphosphide ag(3.73(4))zn(2.27(4))p(16) |
topic | Inorganic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588702/ https://www.ncbi.nlm.nih.gov/pubmed/23468667 http://dx.doi.org/10.1107/S1600536812045667 |
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