The pyrochlore-type molybdate Pr(2)Mo(1.73)Sc(0.27)O(7)

Dipraseodymium molybdenum scandium hepta­oxide, Pr(2)Mo(1.73)Sc(0.27)O(7), crystallizes in the cubic pyrochlore-type structure. In the crystal, (Mo,Sc)O(6) octa­hedra are linked together by common corners, forming a three-dimensional [(Mo,Sc)(2)O(6)] framework. The Pr atom and another O atom atom are located in the voids of this framework. The Mo and the Sc atom are distributed statistically over the same 16d crystallographic position, with site-occupancy factors of 0.867 (3) and 0.133 (3), respectively. The Pr(3+) ions are surrounded by six O atoms from the MoO(6) octa­hedra and by two other O atoms, forming a ditrigonal scalenohedron. All atoms lie on special positions. The Pr and the statistically distributed (Mo,Sc) sites are in the 16c and 16d positions with .-3m symmetry, and two O atoms are in 48f and 8a positions with 2.mm and -43m site symmetry, respectively.