Poly[(μ(3)-pyridine-4-carboxyl­ato-κ(3) O:O′:N)(pyridin-1-ium-4-carboxyl­ato-κO)(thio­cyanato-κN)cobalt(II)]

In the title compound, [Co(C(6)H(5)NO(2))(NCS)(C(6)H(4)NO(2))](n), the Co(2+) cation is coordinated by one N and two O atoms of three bridging pyridine-4-carboxyl­ate anions, one O atom of one zwitterionic pyridinium-4-carboxyl­ate ligand and one terminal N-bonding thio­cyanate anion within a distor...

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Detalles Bibliográficos
Autores principales: Neumann, Tristan, Werner, Julia, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588705/
https://www.ncbi.nlm.nih.gov/pubmed/23468670
http://dx.doi.org/10.1107/S1600536812044431
Descripción
Sumario:In the title compound, [Co(C(6)H(5)NO(2))(NCS)(C(6)H(4)NO(2))](n), the Co(2+) cation is coordinated by one N and two O atoms of three bridging pyridine-4-carboxyl­ate anions, one O atom of one zwitterionic pyridinium-4-carboxyl­ate ligand and one terminal N-bonding thio­cyanate anion within a distorted N(2)O(3) trigonal bipyramid. The bridging coordination mode of the ligands leads to the formation of layers parallel to (-101). N—H⋯O hydrogen-bonding inter­actions within the layers and S⋯S contacts of 3.257 (3) Å between the layers lead to the cohesion of the structure.

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