Poly[(μ(3)-pyridine-4-carboxyl­ato-κ(3) O:O′:N)(pyridin-1-ium-4-carboxyl­ato-κO)(thio­cyanato-κN)cobalt(II)]

In the title compound, [Co(C(6)H(5)NO(2))(NCS)(C(6)H(4)NO(2))](n), the Co(2+) cation is coordinated by one N and two O atoms of three bridging pyridine-4-carboxyl­ate anions, one O atom of one zwitterionic pyridinium-4-carboxyl­ate ligand and one terminal N-bonding thio­cyanate anion within a distor...

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Detalles Bibliográficos
Autores principales: Neumann, Tristan, Werner, Julia, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588705/
https://www.ncbi.nlm.nih.gov/pubmed/23468670
http://dx.doi.org/10.1107/S1600536812044431
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author Neumann, Tristan
Werner, Julia
Jess, Inke
Näther, Christian
author_facet Neumann, Tristan
Werner, Julia
Jess, Inke
Näther, Christian
author_sort Neumann, Tristan
collection PubMed
description In the title compound, [Co(C(6)H(5)NO(2))(NCS)(C(6)H(4)NO(2))](n), the Co(2+) cation is coordinated by one N and two O atoms of three bridging pyridine-4-carboxyl­ate anions, one O atom of one zwitterionic pyridinium-4-carboxyl­ate ligand and one terminal N-bonding thio­cyanate anion within a distorted N(2)O(3) trigonal bipyramid. The bridging coordination mode of the ligands leads to the formation of layers parallel to (-101). N—H⋯O hydrogen-bonding inter­actions within the layers and S⋯S contacts of 3.257 (3) Å between the layers lead to the cohesion of the structure.
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spelling pubmed-35887052013-03-06 Poly[(μ(3)-pyridine-4-carboxyl­ato-κ(3) O:O′:N)(pyridin-1-ium-4-carboxyl­ato-κO)(thio­cyanato-κN)cobalt(II)] Neumann, Tristan Werner, Julia Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(6)H(5)NO(2))(NCS)(C(6)H(4)NO(2))](n), the Co(2+) cation is coordinated by one N and two O atoms of three bridging pyridine-4-carboxyl­ate anions, one O atom of one zwitterionic pyridinium-4-carboxyl­ate ligand and one terminal N-bonding thio­cyanate anion within a distorted N(2)O(3) trigonal bipyramid. The bridging coordination mode of the ligands leads to the formation of layers parallel to (-101). N—H⋯O hydrogen-bonding inter­actions within the layers and S⋯S contacts of 3.257 (3) Å between the layers lead to the cohesion of the structure. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588705/ /pubmed/23468670 http://dx.doi.org/10.1107/S1600536812044431 Text en © Neumann et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Neumann, Tristan
Werner, Julia
Jess, Inke
Näther, Christian
Poly[(μ(3)-pyridine-4-carboxyl­ato-κ(3) O:O′:N)(pyridin-1-ium-4-carboxyl­ato-κO)(thio­cyanato-κN)cobalt(II)]
title Poly[(μ(3)-pyridine-4-carboxyl­ato-κ(3) O:O′:N)(pyridin-1-ium-4-carboxyl­ato-κO)(thio­cyanato-κN)cobalt(II)]
title_full Poly[(μ(3)-pyridine-4-carboxyl­ato-κ(3) O:O′:N)(pyridin-1-ium-4-carboxyl­ato-κO)(thio­cyanato-κN)cobalt(II)]
title_fullStr Poly[(μ(3)-pyridine-4-carboxyl­ato-κ(3) O:O′:N)(pyridin-1-ium-4-carboxyl­ato-κO)(thio­cyanato-κN)cobalt(II)]
title_full_unstemmed Poly[(μ(3)-pyridine-4-carboxyl­ato-κ(3) O:O′:N)(pyridin-1-ium-4-carboxyl­ato-κO)(thio­cyanato-κN)cobalt(II)]
title_short Poly[(μ(3)-pyridine-4-carboxyl­ato-κ(3) O:O′:N)(pyridin-1-ium-4-carboxyl­ato-κO)(thio­cyanato-κN)cobalt(II)]
title_sort poly[(μ(3)-pyridine-4-carboxyl­ato-κ(3) o:o′:n)(pyridin-1-ium-4-carboxyl­ato-κo)(thio­cyanato-κn)cobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588705/
https://www.ncbi.nlm.nih.gov/pubmed/23468670
http://dx.doi.org/10.1107/S1600536812044431
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