Di-μ-hydroxido-bis­[dimeth­yl(thio­cyanato-κN)tin(IV)]

The Sn(IV) atom in the centrosymmetric title complex, [Sn(2)(CH(3))(4)(NCS)(2)(OH)(2)], adopts a distorted trigonal–bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of t...

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Detalles Bibliográficos
Autores principales: Sow, Yaya, Diop, Libasse, Molloy, Kieran C., Kociok-Köhn, Gabriele
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588706/
https://www.ncbi.nlm.nih.gov/pubmed/23468671
http://dx.doi.org/10.1107/S1600536812043462
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author Sow, Yaya
Diop, Libasse
Molloy, Kieran C.
Kociok-Köhn, Gabriele
author_facet Sow, Yaya
Diop, Libasse
Molloy, Kieran C.
Kociok-Köhn, Gabriele
author_sort Sow, Yaya
collection PubMed
description The Sn(IV) atom in the centrosymmetric title complex, [Sn(2)(CH(3))(4)(NCS)(2)(OH)(2)], adopts a distorted trigonal–bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thio­cyanate anion are in the apical >positions. The dinuclear species are linked through O—H⋯S and C—H⋯ S hydrogen-bonding inter­actions into a three-dimensional network.
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spelling pubmed-35887062013-03-06 Di-μ-hydroxido-bis­[dimeth­yl(thio­cyanato-κN)tin(IV)] Sow, Yaya Diop, Libasse Molloy, Kieran C. Kociok-Köhn, Gabriele Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in the centrosymmetric title complex, [Sn(2)(CH(3))(4)(NCS)(2)(OH)(2)], adopts a distorted trigonal–bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thio­cyanate anion are in the apical >positions. The dinuclear species are linked through O—H⋯S and C—H⋯ S hydrogen-bonding inter­actions into a three-dimensional network. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588706/ /pubmed/23468671 http://dx.doi.org/10.1107/S1600536812043462 Text en © Sow et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sow, Yaya
Diop, Libasse
Molloy, Kieran C.
Kociok-Köhn, Gabriele
Di-μ-hydroxido-bis­[dimeth­yl(thio­cyanato-κN)tin(IV)]
title Di-μ-hydroxido-bis­[dimeth­yl(thio­cyanato-κN)tin(IV)]
title_full Di-μ-hydroxido-bis­[dimeth­yl(thio­cyanato-κN)tin(IV)]
title_fullStr Di-μ-hydroxido-bis­[dimeth­yl(thio­cyanato-κN)tin(IV)]
title_full_unstemmed Di-μ-hydroxido-bis­[dimeth­yl(thio­cyanato-κN)tin(IV)]
title_short Di-μ-hydroxido-bis­[dimeth­yl(thio­cyanato-κN)tin(IV)]
title_sort di-μ-hydroxido-bis­[dimeth­yl(thio­cyanato-κn)tin(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588706/
https://www.ncbi.nlm.nih.gov/pubmed/23468671
http://dx.doi.org/10.1107/S1600536812043462
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AT kociokkohngabriele dimhydroxidobisdimethylthiocyanatokntiniv

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