1-[(Z)-1-Ferrocenyl­ethyl­idene]thio­carbonohydrazide

In the title compound, [Fe(C(5)H(5))(C(8)H(11)N(4)S)], the cyclo­penta­dienyl (Cp) rings of the ferrocene unit are close to being eclipsed. They are inclined to one another at an angle of 1.95 (2)° and lie 3.309 (2)Å away from each other. The ethyl­idene­thio­carbonohydrazide fragment is planar, wit...

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Detalles Bibliográficos
Autores principales: Asiri, Abdullah M., Arshad, Muhammad Nadeem, Ishaq, Muhammad, Alamry, Khalid A., Shafiq, Muhammad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588708/
https://www.ncbi.nlm.nih.gov/pubmed/23468673
http://dx.doi.org/10.1107/S1600536812044078
Descripción
Sumario:In the title compound, [Fe(C(5)H(5))(C(8)H(11)N(4)S)], the cyclo­penta­dienyl (Cp) rings of the ferrocene unit are close to being eclipsed. They are inclined to one another at an angle of 1.95 (2)° and lie 3.309 (2)Å away from each other. The ethyl­idene­thio­carbonohydrazide fragment is planar, with an r.m.s. deviation of 0.0347 (2) Å from the mean plane of its eight non-H atoms, and makes dihedral angles of 21.78 (1) and 19.97 (1)° with respect to the two Cp rings. The mol­ecule adopts a trans geometry about the C=N double bond. In the crystal, N—H⋯(N/S) and C—H⋯S inter­actions stack the mol­ecules in an inverse fashion along the b axis.

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