1-[(Z)-1-Ferrocenyl­ethyl­idene]thio­carbonohydrazide

In the title compound, [Fe(C(5)H(5))(C(8)H(11)N(4)S)], the cyclo­penta­dienyl (Cp) rings of the ferrocene unit are close to being eclipsed. They are inclined to one another at an angle of 1.95 (2)° and lie 3.309 (2)Å away from each other. The ethyl­idene­thio­carbonohydrazide fragment is planar, wit...

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Autores principales: Asiri, Abdullah M., Arshad, Muhammad Nadeem, Ishaq, Muhammad, Alamry, Khalid A., Shafiq, Muhammad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588708/
https://www.ncbi.nlm.nih.gov/pubmed/23468673
http://dx.doi.org/10.1107/S1600536812044078
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author Asiri, Abdullah M.
Arshad, Muhammad Nadeem
Ishaq, Muhammad
Alamry, Khalid A.
Shafiq, Muhammad
author_facet Asiri, Abdullah M.
Arshad, Muhammad Nadeem
Ishaq, Muhammad
Alamry, Khalid A.
Shafiq, Muhammad
author_sort Asiri, Abdullah M.
collection PubMed
description In the title compound, [Fe(C(5)H(5))(C(8)H(11)N(4)S)], the cyclo­penta­dienyl (Cp) rings of the ferrocene unit are close to being eclipsed. They are inclined to one another at an angle of 1.95 (2)° and lie 3.309 (2)Å away from each other. The ethyl­idene­thio­carbonohydrazide fragment is planar, with an r.m.s. deviation of 0.0347 (2) Å from the mean plane of its eight non-H atoms, and makes dihedral angles of 21.78 (1) and 19.97 (1)° with respect to the two Cp rings. The mol­ecule adopts a trans geometry about the C=N double bond. In the crystal, N—H⋯(N/S) and C—H⋯S inter­actions stack the mol­ecules in an inverse fashion along the b axis.
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spelling pubmed-35887082013-03-06 1-[(Z)-1-Ferrocenyl­ethyl­idene]thio­carbonohydrazide Asiri, Abdullah M. Arshad, Muhammad Nadeem Ishaq, Muhammad Alamry, Khalid A. Shafiq, Muhammad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(8)H(11)N(4)S)], the cyclo­penta­dienyl (Cp) rings of the ferrocene unit are close to being eclipsed. They are inclined to one another at an angle of 1.95 (2)° and lie 3.309 (2)Å away from each other. The ethyl­idene­thio­carbonohydrazide fragment is planar, with an r.m.s. deviation of 0.0347 (2) Å from the mean plane of its eight non-H atoms, and makes dihedral angles of 21.78 (1) and 19.97 (1)° with respect to the two Cp rings. The mol­ecule adopts a trans geometry about the C=N double bond. In the crystal, N—H⋯(N/S) and C—H⋯S inter­actions stack the mol­ecules in an inverse fashion along the b axis. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588708/ /pubmed/23468673 http://dx.doi.org/10.1107/S1600536812044078 Text en © Asiri et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Asiri, Abdullah M.
Arshad, Muhammad Nadeem
Ishaq, Muhammad
Alamry, Khalid A.
Shafiq, Muhammad
1-[(Z)-1-Ferrocenyl­ethyl­idene]thio­carbonohydrazide
title 1-[(Z)-1-Ferrocenyl­ethyl­idene]thio­carbonohydrazide
title_full 1-[(Z)-1-Ferrocenyl­ethyl­idene]thio­carbonohydrazide
title_fullStr 1-[(Z)-1-Ferrocenyl­ethyl­idene]thio­carbonohydrazide
title_full_unstemmed 1-[(Z)-1-Ferrocenyl­ethyl­idene]thio­carbonohydrazide
title_short 1-[(Z)-1-Ferrocenyl­ethyl­idene]thio­carbonohydrazide
title_sort 1-[(z)-1-ferrocenyl­ethyl­idene]thio­carbonohydrazide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588708/
https://www.ncbi.nlm.nih.gov/pubmed/23468673
http://dx.doi.org/10.1107/S1600536812044078
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