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catena-Poly[[[diaqua(1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2) N (3):O (6)] sesquihydrate}
In the title compound, {[Co(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), the Co(II) atom is hexacoordinated by one N atom and one O atom from two symmetry-related 1H-benzimidazole-5,6-dicarboxylate ligands, two N atoms from one 1,10-phenanthroline ligand (phen) and two water molecule...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588709/ https://www.ncbi.nlm.nih.gov/pubmed/23468674 http://dx.doi.org/10.1107/S1600536812043760 |
Sumario: | In the title compound, {[Co(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), the Co(II) atom is hexacoordinated by one N atom and one O atom from two symmetry-related 1H-benzimidazole-5,6-dicarboxylate ligands, two N atoms from one 1,10-phenanthroline ligand (phen) and two water molecules. The dihedral angle between the 1H-benzimidazole-5,6-dicarboxylate and 1,10-phenanthroline ligands is 74.41 (4)°. The crystal packing is governed by intermolecular O—H⋯O and N—H⋯O hydrogen-bonding interactions. All water (coordinating and lattice) molecules take part in the hydrogen-bonding interactions. In addition, there are π–π stacking interactions between inversion-related phen ligands, the shortest centroid–centroid distance being 3.7536 (16) Å. One of the two lattice water molecules shows half-occupancy. |
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