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catena-Poly[[[diaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxyl­ato-κ(2) N (3):O (6)] sesquihydrate}

In the title compound, {[Co(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), the Co(II) atom is hexa­coordinated by one N atom and one O atom from two symmetry-related 1H-benzimidazole-5,6-dicarboxyl­ate ligands, two N atoms from one 1,10-phenanthroline ligand (phen) and two water mol­ecule...

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Detalles Bibliográficos
Autores principales: Xu, Dong-Bo, Fang, Yu, Jiang, De-Li, Zhu, Yu, Chen, Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588709/
https://www.ncbi.nlm.nih.gov/pubmed/23468674
http://dx.doi.org/10.1107/S1600536812043760
Descripción
Sumario:In the title compound, {[Co(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), the Co(II) atom is hexa­coordinated by one N atom and one O atom from two symmetry-related 1H-benzimidazole-5,6-dicarboxyl­ate ligands, two N atoms from one 1,10-phenanthroline ligand (phen) and two water mol­ecules. The dihedral angle between the 1H-benzimidazole-5,6-dicarboxyl­ate and 1,10-phenanthroline ligands is 74.41 (4)°. The crystal packing is governed by inter­molecular O—H⋯O and N—H⋯O hydrogen-bonding inter­actions. All water (coordin­ating and lattice) mol­ecules take part in the hydrogen-bonding inter­actions. In addition, there are π–π stacking inter­actions between inversion-related phen ligands, the shortest centroid–centroid distance being 3.7536 (16) Å. One of the two lattice water molecules shows half-occupancy.