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catena-Poly[[[diaqua(1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2) N (3):O (6)] sesquihydrate}
In the title compound, {[Co(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), the Co(II) atom is hexacoordinated by one N atom and one O atom from two symmetry-related 1H-benzimidazole-5,6-dicarboxylate ligands, two N atoms from one 1,10-phenanthroline ligand (phen) and two water molecule...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588709/ https://www.ncbi.nlm.nih.gov/pubmed/23468674 http://dx.doi.org/10.1107/S1600536812043760 |
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author | Xu, Dong-Bo Fang, Yu Jiang, De-Li Zhu, Yu Chen, Min |
author_facet | Xu, Dong-Bo Fang, Yu Jiang, De-Li Zhu, Yu Chen, Min |
author_sort | Xu, Dong-Bo |
collection | PubMed |
description | In the title compound, {[Co(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), the Co(II) atom is hexacoordinated by one N atom and one O atom from two symmetry-related 1H-benzimidazole-5,6-dicarboxylate ligands, two N atoms from one 1,10-phenanthroline ligand (phen) and two water molecules. The dihedral angle between the 1H-benzimidazole-5,6-dicarboxylate and 1,10-phenanthroline ligands is 74.41 (4)°. The crystal packing is governed by intermolecular O—H⋯O and N—H⋯O hydrogen-bonding interactions. All water (coordinating and lattice) molecules take part in the hydrogen-bonding interactions. In addition, there are π–π stacking interactions between inversion-related phen ligands, the shortest centroid–centroid distance being 3.7536 (16) Å. One of the two lattice water molecules shows half-occupancy. |
format | Online Article Text |
id | pubmed-3588709 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887092013-03-06 catena-Poly[[[diaqua(1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2) N (3):O (6)] sesquihydrate} Xu, Dong-Bo Fang, Yu Jiang, De-Li Zhu, Yu Chen, Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Co(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), the Co(II) atom is hexacoordinated by one N atom and one O atom from two symmetry-related 1H-benzimidazole-5,6-dicarboxylate ligands, two N atoms from one 1,10-phenanthroline ligand (phen) and two water molecules. The dihedral angle between the 1H-benzimidazole-5,6-dicarboxylate and 1,10-phenanthroline ligands is 74.41 (4)°. The crystal packing is governed by intermolecular O—H⋯O and N—H⋯O hydrogen-bonding interactions. All water (coordinating and lattice) molecules take part in the hydrogen-bonding interactions. In addition, there are π–π stacking interactions between inversion-related phen ligands, the shortest centroid–centroid distance being 3.7536 (16) Å. One of the two lattice water molecules shows half-occupancy. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588709/ /pubmed/23468674 http://dx.doi.org/10.1107/S1600536812043760 Text en © Xu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xu, Dong-Bo Fang, Yu Jiang, De-Li Zhu, Yu Chen, Min catena-Poly[[[diaqua(1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2) N (3):O (6)] sesquihydrate} |
title |
catena-Poly[[[diaqua(1,10-phenanthroline-κ(2)
N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2)
N
(3):O
(6)] sesquihydrate} |
title_full |
catena-Poly[[[diaqua(1,10-phenanthroline-κ(2)
N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2)
N
(3):O
(6)] sesquihydrate} |
title_fullStr |
catena-Poly[[[diaqua(1,10-phenanthroline-κ(2)
N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2)
N
(3):O
(6)] sesquihydrate} |
title_full_unstemmed |
catena-Poly[[[diaqua(1,10-phenanthroline-κ(2)
N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2)
N
(3):O
(6)] sesquihydrate} |
title_short |
catena-Poly[[[diaqua(1,10-phenanthroline-κ(2)
N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ(2)
N
(3):O
(6)] sesquihydrate} |
title_sort | catena-poly[[[diaqua(1,10-phenanthroline-κ(2)
n,n′)cobalt(ii)]-μ-1h-benzimidazole-5,6-dicarboxylato-κ(2)
n
(3):o
(6)] sesquihydrate} |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588709/ https://www.ncbi.nlm.nih.gov/pubmed/23468674 http://dx.doi.org/10.1107/S1600536812043760 |
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