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catena-Poly[[[diaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxyl­ato-κ(2) N (3):O (6)] sesquihydrate}

In the title compound, {[Co(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), the Co(II) atom is hexa­coordinated by one N atom and one O atom from two symmetry-related 1H-benzimidazole-5,6-dicarboxyl­ate ligands, two N atoms from one 1,10-phenanthroline ligand (phen) and two water mol­ecule...

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Detalles Bibliográficos
Autores principales: Xu, Dong-Bo, Fang, Yu, Jiang, De-Li, Zhu, Yu, Chen, Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588709/
https://www.ncbi.nlm.nih.gov/pubmed/23468674
http://dx.doi.org/10.1107/S1600536812043760
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author Xu, Dong-Bo
Fang, Yu
Jiang, De-Li
Zhu, Yu
Chen, Min
author_facet Xu, Dong-Bo
Fang, Yu
Jiang, De-Li
Zhu, Yu
Chen, Min
author_sort Xu, Dong-Bo
collection PubMed
description In the title compound, {[Co(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), the Co(II) atom is hexa­coordinated by one N atom and one O atom from two symmetry-related 1H-benzimidazole-5,6-dicarboxyl­ate ligands, two N atoms from one 1,10-phenanthroline ligand (phen) and two water mol­ecules. The dihedral angle between the 1H-benzimidazole-5,6-dicarboxyl­ate and 1,10-phenanthroline ligands is 74.41 (4)°. The crystal packing is governed by inter­molecular O—H⋯O and N—H⋯O hydrogen-bonding inter­actions. All water (coordin­ating and lattice) mol­ecules take part in the hydrogen-bonding inter­actions. In addition, there are π–π stacking inter­actions between inversion-related phen ligands, the shortest centroid–centroid distance being 3.7536 (16) Å. One of the two lattice water molecules shows half-occupancy.
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spelling pubmed-35887092013-03-06 catena-Poly[[[diaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxyl­ato-κ(2) N (3):O (6)] sesquihydrate} Xu, Dong-Bo Fang, Yu Jiang, De-Li Zhu, Yu Chen, Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Co(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), the Co(II) atom is hexa­coordinated by one N atom and one O atom from two symmetry-related 1H-benzimidazole-5,6-dicarboxyl­ate ligands, two N atoms from one 1,10-phenanthroline ligand (phen) and two water mol­ecules. The dihedral angle between the 1H-benzimidazole-5,6-dicarboxyl­ate and 1,10-phenanthroline ligands is 74.41 (4)°. The crystal packing is governed by inter­molecular O—H⋯O and N—H⋯O hydrogen-bonding inter­actions. All water (coordin­ating and lattice) mol­ecules take part in the hydrogen-bonding inter­actions. In addition, there are π–π stacking inter­actions between inversion-related phen ligands, the shortest centroid–centroid distance being 3.7536 (16) Å. One of the two lattice water molecules shows half-occupancy. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588709/ /pubmed/23468674 http://dx.doi.org/10.1107/S1600536812043760 Text en © Xu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Dong-Bo
Fang, Yu
Jiang, De-Li
Zhu, Yu
Chen, Min
catena-Poly[[[diaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxyl­ato-κ(2) N (3):O (6)] sesquihydrate}
title catena-Poly[[[diaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxyl­ato-κ(2) N (3):O (6)] sesquihydrate}
title_full catena-Poly[[[diaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxyl­ato-κ(2) N (3):O (6)] sesquihydrate}
title_fullStr catena-Poly[[[diaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxyl­ato-κ(2) N (3):O (6)] sesquihydrate}
title_full_unstemmed catena-Poly[[[diaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxyl­ato-κ(2) N (3):O (6)] sesquihydrate}
title_short catena-Poly[[[diaqua­(1,10-phenanthroline-κ(2) N,N′)cobalt(II)]-μ-1H-benzimidazole-5,6-dicarboxyl­ato-κ(2) N (3):O (6)] sesquihydrate}
title_sort catena-poly[[[diaqua­(1,10-phenanthroline-κ(2) n,n′)cobalt(ii)]-μ-1h-benzimidazole-5,6-dicarboxyl­ato-κ(2) n (3):o (6)] sesquihydrate}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588709/
https://www.ncbi.nlm.nih.gov/pubmed/23468674
http://dx.doi.org/10.1107/S1600536812043760
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